Metal Complexes of D-Glucosamine and its Derivatives. V. Spectrophotometric Investigations on Copper (II), Nickel (II), and Cobalt (II) Complexes of D-Glucosamine and the Preparation of Glucosamine-copper Complex

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概要

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• Spectrophotometric behaviors of copper-, nickel-, and cobalt-complexes of D-glucosamine (I) were investigated in visible region. It was found that three metal ions formed a complex having a 1 : 1 ratio of I to a metal ion respectively. Equilibrium and stability constants were also determined by the application of McConnel-Davidson's method. Both stability constants of copper- and cobalt-complexes were of the same magntitude, but that of nickel-complex was lower than the other. A possibility of the presence of the hydroxo complex in the complex formation between I and metal ions was also ascertained by the analysis of the spectra at near ultraviolet region. Futhermore, the preparation of copper complex in solid state was carried out, and a 1 : 1 complex was obtained. From the analysis of the prepared complex, GCu(OH)Cl seemed to be the most probable experimental formula for the complex.

• 公益社団法人日本薬学会の論文
• 1965-03-25

著者

• 田村 善蔵

  Faculty of Pharmaceutical Sciences, University of Tokyo

• 宮崎 元一

  金沢大学薬学部

• 宮崎 元一

  Faculty of Pharmaceutical Sciences, Kanazawa University

• 田村 善蔵

  Faculty Of Pharmaceutical Sciences University Of Tokyo

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