A Simple Determination Method of the Absolute Configuration of 1-Arylethanthiols by an Intramolecular CH/π Shielding Effect in ^1H-NMR of Diastereomeric Thiol Esters

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概要

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• A simple method for the determination of the absolute configuration of 1-arylethanthiols was achieved by the observation of an intramolecular CH/π shielding effect in ^1H-NMR of the corresponding thiol esters. (S)-Isomer of the diastereomers always shows remarkable shielding effect.

• 公益社団法人日本薬学会の論文
• 2003-04-01

著者

• 北 泰行

  大阪大学大学院薬学研究科

• 北 泰行

  大阪大学薬学部

• KITA Yasuyuki

  Graduate School of Pharmaceutical Sciences, Osaka University

• Kita Yasuyuki

  Graduate School Of Pharmaceutical Sciences Osaka Univ.

• Kita Yasuyuki

  Graduate School Of Pharmaceutical Sciences Osaka University Yamadaoka

• Itoh K

  Medicinal Chemistiy Research Laboratories I Pharmaceutical Research Division Takeda Chemical Industr

• Itoh K

  Pharmaceutical Research Laboratories Iii Pharmaceutical Research Division Takeda Chemical Industries

• MATSUGI Masato

  Department of Materials Chemistry, Graduate School of Engineering, Osaka University

• NOJIMA Masatomo

  Department of Materials Chemistry & Frontier Research Center, Graduate School of Engineering, Osaka

• HAGIMOTO Yuri

  Graduate School of Pharmaceutical Sciences, Osaka University

• ITOH Kinuyo

  Department of Materials Chemistry & Frontier Research Center, Graduate School of Engineering. Osaka

• Itoh Kinuyo

  Department Of Materials Chemistry & Frontier Research Center Graduate School Of Engineering. Osa

• Hagimoto Yuri

  Graduate School Of Pharmaceutical Sciences Osaka University

• Matsugi M

  Department Of Materials Chemistry & Frontier Research Center Graduate School Of Engineering. Osa

• Nojima Masatomo

  Department Of Materials Chemistry & Frontier Research Center Graduate School Of Engineering. Osa

• Nojima Masatomo

  Department Of Material Chemistry Faculty Of Engineering Osaka University

• Matsugi Masato

  Department of Applied Biological Chemistry, Faculty of Agriculture, Meijo University

• Nojima Masatomo

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

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