Chemistry of Silylketenes : Simple Preparation of Silylallenes by the Reaction of Silyketenes with Phosphorus Ylides
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概要
- 論文の詳細を見る
Reaction of silylketenes 1a, b with stabilized ylides 2a-e readily gave silylallenes 3a-f in high yields. However, similar reaction of 1a with the less stable ylides 2f, g resulted in low yields of the allenes 3 g, h. Use of silylketenes 5a, c with an additional trimethylsilyl group overcame this problem to give silylallenes 3c, g-k directly in considerable to good yields. In this reaction, the additional trimethylsilyl group apparently worked as a masking group.
- 社団法人日本薬学会の論文
- 1994-02-15
著者
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北 泰行
Faculty of Pharmaceutical Sciences, Osaka University
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北 泰行
大阪大学大学院薬学研究科
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北 泰行
大阪大学薬学部
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赤井 周司
大阪大学大学院薬学研究科
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Kita Yasuyuki
Graduate School Of Pharmaceutical Sciences Osaka University Yamadaoka
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筑木 保知
Faculty of Pharmaceutical Sciences, Osaka University
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北垣 伸治
Faculty of Pharmaceutical Sciences, Osaka University
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赤井 周司
Faculty of Pharmaceutical Sciences, Osaka University
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筑木 保知
Faculty Of Pharmaceutical Sciences Osaka University
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北垣 伸治
Faculty Of Pharmaceutical Sciences Osaka University
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北 泰行
Faculty Of Pharmaceutical Sciences Osaka University
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