An Extended INDO-Cl Study on Protonated Retinal Schiff-Base

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概要

• 論文の詳細を見る

• The bond lengths, bond orders, electron densities and optical absorption of theground state of retinal forming a protonated Schiff-base linkage with a lysine residue(PRSB-Lys) are calculated using the extended INDO-Cl molecular orbital method,and the result is compared with the previotus one obtained by the m-electron approx-imation. It is, thus, shown that the r-electron system of PRSB-Lys is appreciablypolarized, and that the o -n interaction in PRSB-Lys is too large to be neglectedwhen a C-C bond in its polyene chain is twisted. It is also shown that the negativecounter point-charge exerts influence on the ;m-electron distribution in a similar wayto that shown by the m-electron approximation.

• 社団法人日本物理学会の論文
• 1990-10-15

著者

• Suzuki Hideo

  Department of Information and Network Science, Chiba Institute of Technology

• 鈴木 秀男

  慶應義塾大学

• Ito Etsuro

  北海道大学 理研究

• 鈴木 秀男

  University Of Tsukuba

• Ito Etsuro

  Advanced Research Center For Human Sciences Waseda University

• Ito E

  Divisions Of Biological Sciences Hokkaido University

• Sakurai H

  Nanomaterials Laboratory National Institute For Materials Science

• Suzuki H

  National Inst. Materials Sci. Ibaraki

• Sugimoto Tohru

  Biophysics Laboratory College Of Engineering Kanto Gakuin University

• Suzuki H

  Waseda Univ. Tokyo

• Sugimoto Toyonari

  Research Institute For Advanced Science And Technology Osaka Prefecture University

• KISHI Yoshio

  Department of Physics,School of Science and Engineering,Waseda University

• Ito E

  Division Of Innovative Research Creative Research Initiative "sousei" Hokkaido University:

• Ito E

  Institute For Study Of The Earth's Interior Okayama University

• Sugimoto T

  Toyota Motor Corporation

• Kishi Yoshio

  Department Of Physics School Of Science And Engineering Waseda University

• Suzuki Hideo

  Department Of Cardiology Surugadai Nihon University Hospital

• Suzuki Hideo

  Department of Bioscience Research, Tsukuba Research Laboratory, Toagosei Co., Ltd.

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