Adiabatic Potentials for cis-trans Isomerization of Protonated Retinal Schiff-Base with Counter Change
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概要
- 論文の詳細を見る
On the protonated retinal Schiff-base interacting with a counter point-charge, the adiabatic potentials of the singlet and triplet states of π-electrons are calculated as functions of the angle θ of rotation about the C^<11>-C_<12> (double) or the C-<10>-C_<11> (single) bond, according to our previous formulation and parametrization. It is shown that the cis-trans isomerization around the double bond is characterized by the close approach of adiabatic potentials of the first- and the second-excited singlet state in the vicinity of θ=40° or 140°, not by the crossing between singlet and tirplet states as concluded in the previous two papers. It is also shown that the corresponding eigenfunctions exchange their characters in the small region of approach, and that a similar exchange also occurs at 90° between the ground and the first-excited singlet, although it is not so complete as that at about 40° or 140°.
- 社団法人日本物理学会の論文
- 1974-09-15
著者
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Suzuki Hideo
Department of Information and Network Science, Chiba Institute of Technology
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NAKACHI Kei
Department of Radiobiology/Molecular Epidemiology, Radiation Effects Research Foundation
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Nakachi Kei
Department Of Physics School Of Science And Engineering Waseda University
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Nakachi Kei
放射線影響研究所 放射線生物学･分子疫学部
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Nakachi Kei
Department Of Epidemiology Radiation Effects Research Institute
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KOMATSU Toshiro
Department of Physics, School of Science and Engineering, Waseda University
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Komatsu Toshiro
Department Of Dermatology School Of Medicine Iwate Medical University
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Komatsu Tokutaro
Graduate School Of Arts & Sciences The University Of Tokyo
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Komatsu Tokutaro
Department Of Chemistry Graduate School Of Science Kyoto University
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Komatsu T
Osaka Univ. Osaka
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Suzuki Hideo
Department Of Cardiology Surugadai Nihon University Hospital
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Suzuki Hideo
Department of Physics, School of Science and Engineering, Waseda University
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Suzuki Hideo
Department of Bioscience Research, Tsukuba Research Laboratory, Toagosei Co., Ltd.
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