On the Role of the Change in Bond Lengths in the Photoisomerization of Rhodopsin Chromophore
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概要
- 論文の詳細を見る
On the m-electron system of PRSB with its counter point-charge, we considersuch "deformed" excited state that has different bond lengths for stabilizationfrom those in the excited state immediately after the absorption of light, togetherwith "virtual" ground state having the same bond lengths as the deformedexcited state. And we calculate their adiabatic potentials and net-charge distribu-tions for the respective cases of cis-trans isomerization around single and doublebonds. It is shown that a close approach of adiabatic potentials between thedeformed excited and virtual ground states occurs only in the case around Cz .-C..bond, and that only the case around C..-C.. or C.3-C.. bond generates arapid reciprocating motion (a large transient polarization) of net charges in thedeformed excited state (in the virtual ground state in the region of the orthogonalconformation).
- 社団法人日本物理学会の論文
- 1984-07-15
著者
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Suzuki Hideo
Department Of Cardiology Surugadai Nihon University Hospital
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YOSHIDA Ohki
Department of Physics,School of Science and Engineering,Waseda University
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KOSEKO Yasushi
Department of Physics,School of Science and Engineering,Waseda University
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Yoshida Ohki
Department Of Physics School Of Science And Engineering Waseda University
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Koseko Yasushi
Department Of Physics School Of Science And Engineering Waseda University
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Suzuki Hideo
Department of Bioscience Research, Tsukuba Research Laboratory, Toagosei Co., Ltd.
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