Adiabatic Potential for cis-trans Isomerization of Rhodopsin Chromophore in the Deformed Excited State
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概要
- 論文の詳細を見る
On the protonated retinal Schiff-base (PRSB) interacting with counter pointcharge e, the adiabatic potential for cis-trans isomerization of the first singletexcited-state is calculated as a function of rotation angle 0.. .. about C..-C..bond, including the effects of the deformation in geometrical structure of theexcited state after the absorption of light.It is shown that the potential curve of this deformed excited state is barrierlessand downward concave whereas that of the ground state is upward convex, andthat the two curves intersect in the vicinity of 0.. ..=90'. It is also shown that,in the highly twisted conformation at 0..-..=90', the defon'med excited stateis considerably polarized with almost positive charge ?e? shifted into C..-N.".fragment, so that the effect of e on the adiabatic potential of the deformed excitedstate is important.
- 社団法人日本物理学会の論文
- 1982-11-15
著者
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Suzuki Hideo
Department of Information and Network Science, Chiba Institute of Technology
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Ishikawa Ken
Department Of Organic And Polymeric Materials Tokyo Institute Of Technology
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Yoshihara Toru
Department Of Physics School Of Science And Engineering Waseda University
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Suzuki Hideo
Department Of Cardiology Surugadai Nihon University Hospital
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Suzuki Hideo
Department of Bioscience Research, Tsukuba Research Laboratory, Toagosei Co., Ltd.
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Suzuki Hideo
Department of Physics,School of Science and Engineering Waseda University
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ISHIKAWA Ken
Department of Applied Physics, University of Tokyo
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Ishikawa Ken
Department of Physics,School of Science and Engineering Waseda University:Research and Development Center,Hitachi Medical Corporation
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