On the Theory of 3-Methyl Lumiflavin in Solution
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概要
- 論文の詳細を見る
The absorption spectrum of 3-methyl lumiflavin in soltttion is reexamined byour previous formulation for m-electron systems, improving the previous estima-tion of the ratio of oscillator strength of the second to the first absorption band.It is found that the following two screenings are necessary to reproduce the absorp-tion spectrum in benzene: (1) the screening of two-center Coulomb repulsionintegrals for all the pairs of atoms except bonded ones; (2) that of the effectivenuclear charges Z' determined by Julg's method for Slater-type 2p,-orbitals. It isalso found that the absorption spectrum in ethanol or water can be explainedby the model of 3-methyl lumiflavin :interacting with two point-dipoles. Theangle between the transition moments of the first and second bands is foundto be at most 44.4' in benzene, 44.3' in ethanol and 45.8' in water.
- 社団法人日本物理学会の論文
- 1980-03-15
著者
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Suzuki Hideo
Department of Information and Network Science, Chiba Institute of Technology
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Sugimoto Tohru
Pl Gakuen Women's Junior College
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NAKANO Katsuyuki
Department of Chemical Engineering, Faculty of Engineering, Fukuoka Univeristy
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Nakano Katsuyuki
Department Of Physics School Of Science And Engineering Waseda University
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Nakano Katsuyuki
Department Of Chemical Engineering Faculty Of Engineering Fukuoka Univeristy
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Suzuki Hideo
Department Of Cardiology Surugadai Nihon University Hospital
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Suzuki Hideo
Department Of Physics School Of Science And Engineering Waseda University
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Suzuki Hideo
Department of Bioscience Research, Tsukuba Research Laboratory, Toagosei Co., Ltd.
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