Models for the Structural Change of Phytochrome Chromophore Accompanied by cis-trans Isomerization and Proton Transfer

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概要

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• The effect of a point-charge and a point-dipole on the optical absorption ofphytochromobilin is calculated according to our previous LCAO-ASMO-SCF-Clmethod for m-electrons. It is thus shown that the optical absorption of phytochromecan be reproduced by the following model including cis-trans isomerization andproton transfer: in the P.+P.. conversion, the terminal pyrrole ring D rotatesaround the double bond of its adjacent methyne bridge, and a proton is trans-ferred to the nitrogen in pyrrole ring B from its neighboring amino acid residue.

• 社団法人日本物理学会の論文
• 1985-01-15

著者

• Suzuki Hideo

  Department of Information and Network Science, Chiba Institute of Technology

• SAITO Minoru

  Department of Internal Medicine, Nagoya Ekisaikai Hospital

• Sugimoto Tohru

  Pl Gakuen Women's Junior College

• Sugimoto Toyonari

  Research Institute For Advanced Science And Technology Osaka Prefecture University

• Sugimoto T

  Toyota Motor Corporation

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