Theory of Rhodopsin Chromophore and Its Desmethyl Analogues.II

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概要

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• We assume such a model for rhodopsin chromophore that 11-cis PRSBinteracts notonly with its negative counter charge near Np but also with an ion-pair[C00 - - - X"l in the vucunuty of CH. on C,. And we calculate the optical absorptionsof desmethyl analogues of rhodopsin in much the same way as the previous paper.It is shown that the observed 2 ...,;s of desmethyl analogues of rhodopsin canreasonably be explained by taking into account the structural change of PRSB andconfigurational change of [C00 . . . X"l due to the methyl substitution byhydrogen(s). It is also shown that the previous treatment of "partially-deprotonated"OH group is not fully appropriate to the present case of COOH since the degree ofdeprotonation is calculated to be as large as 0.4.

• 社団法人日本物理学会の論文
• 1982-03-15

著者

• Suzuki Hideo

  Department of Information and Network Science, Chiba Institute of Technology

• Wada Naohisa

  Department Of Physics Of General Education School Of Engineering Toyo University

• Wada Naohisa

  Department Of Applied Chemistry And Biotechnology Graduate School Of Engineering University Of Fukui

• Kitajima Hiroki

  Department of Cardiology, Kouseikai Takeda Hospital

• Kitajima Hiroki

  Department Of Cardiology Kouseikai Takeda Hospital

• Suzuki Hideo

  Department Of Cardiology Surugadai Nihon University Hospital

• Suzuki Hideo

  Department of Bioscience Research, Tsukuba Research Laboratory, Toagosei Co., Ltd.

• Kitajima Hiroki

  Department of Physics,School of Science and Engineering,Waseda University

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