Charge Segregation in the Metal-Insulator Transition of the Thiospinel Cu_<1-x>Zn_xIr_2S_4 : Condensed Matter: Structure, etc.
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概要
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The metal-insulator transition (MIT) in the thiospinel Cu_<1-x>Zn_xIr_2S_4 has been investigated by means of ^<63>Cu NMR. We find that the sample with x = 0.3, having a uniform metallic phase at room temperature, exhibits a phase separation into the metallic and insulating regions below T_<MI> ~70 K, where the first order MIT is observed In the resistivity data. The insulating regions have the same Cu Knight shift as that in the diamagnetic insulator at x = O. This indicates that the charge density in the low-T insulating phase is invariant, which causes the carriers introduced by the Zn substitution to be segregated from the insulating regions. Based on these observations, a possible mechanism of the MIT is discussed.
- 社団法人日本物理学会の論文
- 2001-01-15
著者
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SUZUKI Hiroyuki
National Institute for Materials Science
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Shimizu T
National Institute For Materials Science
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SUZUKI Hitoshi
Tohoku Gakuin University
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鈴木 秀男
慶應義塾大学
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鈴木 秀男
University Of Tsukuba
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Matsumoto T
Kyoto Univ. Kyoto
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Sakurai H
Nanomaterials Laboratory National Institute For Materials Science
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SHIMIZU Tadashi
National Research Institute for Metals
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Kitazawa Hideaki
National Institute For Materials Science
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Kitazawa Hideaki
The Institute Of Physical And Chemical Research Riken
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Kitazawa Hideaki
Nanomaterials Laboratory National Institute For Materials Science
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Suzuki H
National Inst. Materials Sci. Ibaraki
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Suzuki H
National Research Institute For Metals
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MATSUMOTO Takehiko
National Research Institute for Metals
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GOTO Atsushi
National Institute for Materials Science
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CAO Guanghan
National Research Institute for Metals
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Kitazawa Hideaki
National Institute For Material Science
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Kitazawa Hideaki
Physical Properties Division National Research Institute For Metals
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Shimizu Tadashi
National Inst. For Materials Sci.
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Shimizu Tadashi
Advanced Nano Characterization Center National Institute For Materials Science
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Shimizu T
National Inst. Materials Sci. Ibaraki Jpn
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Kitazawa Hideaki
The Institute Of Physical And Chemical Research
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Suzuki H
Waseda Univ. Tokyo
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Shibuya T
Univ. Tokyo Tokyo Jpn
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Matsumoto T
National Research Institute For Metals
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Matsumoto T
Materials Engineering Laboratory National Institute Of Materials Science
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Matsumoto T
Institute For Solid State Physics The University Of Tokyo
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Matsumoto Takehiko
National Institute For Materials Science
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Kitazawa H
National Institute For Materials Science (nims)
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Goto Atsushi
National Research Institute For Metals
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Goto Atsushi
Institute For Solid State Physics University Of Tokyo
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Shimizu T
National Research Laboratory For Metal
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Goto A
National Research Laboratory For Metal
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Suzuki Hiroyuki
National Institute For Material Science
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Matsumoto Takehiko
Institute For Solid State Physics The University Of Tokyo
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Suzuki H
Tohoku Gakuin University
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Goto Atsushi
National Institute for Materials Science (NIMS)
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