A Molecular Statistical Theory of Smectic A Liquid Crystalline Mixtures:Thermal Stability of Smectic A Phase in Binary Mixtures
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概要
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A molecular statistical theory of smectic A liquid crystalline mixtures is pre-sented. Both the intermolecular repulsions and the attractions are consistentlyintroduced in similar to the previous work on smectic A liquid crystals." Therepulsive interaction is approximated in terms of the hard-core potential andis taken into account within the second-virial approximation. The temperaturedependence of the order parameters over the smectic-nematic (or isotropic)and nematic-isotropic phase transitions is numerically calculated for several binarymixtures. In addition the phase diagrams of them are constructed. The smectic-nem2tic (or isotropic) transition temperatures in binary mixtures tend to beincreased in comparison with the predicted values in terms of the linear approxima-tion, being consistent with some experimental findings. It is also found that thesymmetry-breaking component of one-body pseudo-potential contributes to thethermal stability of smectic A phase in smectic A binary mixtures.
- 社団法人日本物理学会の論文
- 1985-01-15
著者
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NAKAGAWA Masahiro
Department of Electrical Engineering, Faculty of Engineering, Nagaoka University of Technology
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Akahane Tadashi
Deparment Of Electrical Engineering Faculty Of Engineering The Technological University Of Nagaoka
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Nakagawa Masahiro
Deparment Of Electrical Engineering Faculty Of Engineering Nagaoka University Of Technology
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