Valence-Band Structures of Quasi-One-Dimensional Crystals C_5H_10NH_2PbX_3 [X = I, Br](Condensed Matter : Electronic Structure, Electrical, Magnetic and Optical Properties)
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概要
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X-ray and ultra-violet photoemission spectra have been measured to study the valence-band structures of piperidinium trihaloplumbates. C_5H_10NH_2PbX_3 [X = I, Br], which have natural nano-scale one-dimensional structures. The valence-band spectra of lead halides, which have the three-dimensional structures, are also reported for comparison. The partial densities of states related to the constituent ions and molecules were obtained with the comparison between the XPS and UPS. Empirical LCAO calculations were also carried out to analyze the experimental results. The quantum-well-like electronic structure in C_5H_10NH_2PbX_3 [X = I, Br] is proposed.
- 社団法人日本物理学会の論文
- 2002-11-15
著者
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Tanaka K
Institute Of Earth And Space Science Graduate School Of Science Osaka University
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TANAKA Koichiro
Department of Physics,Graduate School of Science,Kyoto University
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Kamada M
Tokyo Inst. Of Technol. Tokyo
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Kamada Masao
Synchrotornlight Application Center Saga University
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Kanno K
Department Of Material Science And Chemistry Wakayamna University
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Tanaka K
Department Of Physics Graduate School Of Science Kyoto University
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AZUMA Junpei
Department of Physics, Kyoto University
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KAMADAI Masao
UVSOR Facility, Institute for Molecular Science
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Azuma J
Department Of Physics Kyoto University
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Azuma Junpei
Department Of Physics Kyoto University
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Tanaka Koichiro
Department Of Physics Kyoto University:inst. For Integrated Cell-material Sic. (icems) Kyoto Univ.
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Kamada Masao
Uvsor Facility For Molecular Science
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Tanaka Koichiro
Department Of Applied Biological Sciences Saga University
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Kan'no Ken-ichi
Department Of Physics Faculty Of Science Kyoto University
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KAN'NO Ken-ichi
Department of Material Science and Chemistry, Wakayamna University
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