Stereoselective Synthesis of Some Isomers of Dodecadien-1-ol: Compounds Related to the Pine Moth Sex Pheromone
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概要
- 論文の詳細を見る
Four isomers of 5, 7-dodecadien-1-ol were previously proposed as being the sex pheromone of the pine moth. The isomers were stereoselectively synthesized from 1-hexyne and tetrahydropyranyl ether of 5-hexyn-1-ol. The (5Z, 7Z)-isomer was synthesized by a Chodkiewic Cadiot reaction followed by hydroboration, and other three isomers by novel synthetic methods including the addition of zirconocene hydride [Schwarzs reagent (C5H5)2Zn(H)Cl] to control the regioselective coupling reaction. The 5, 8- and 5, 9-dodecadien-1-ols were also synthesized by similar methods for comparison of their characteristics with the endogenous sex pheromone.
- 社団法人 日本農芸化学会の論文
著者
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TAKAHASHI Nobutaka
Department of Biochemistry University of Shizuoka School of Pharmaceutical Science
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Ando T
Department Of Applied Biological Science Faculty Of Agriculture Tokyo University Of Agriculture And
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Yoshida Shigeo
Department Of Internal Medicine Division I Kobe University School Of Medicine
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AND Tetsu
The Institute of Physical and Chemical Research
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VU Manh
Department of Agricultural Chemistry, Faculty of Agriculture, The University of Tokyo
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Vu Manh
Department Of Agricultural Chemistry Faculty Of Agriculture The University Of Tokyo
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Takahashi Nobutaka
Department Of Agricultural Chemistry Faculty Of Agricultural Science University Of Tokyo
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Yoshida Shigeo
Department Of Agricultural Chemistry Faculty Of Agriculture University Of Tokyo
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YOSHIDA Shigeo
Department of Agricultural Chemistry, Faculty of Agriculture, The University of Tokyo
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