Mass Spectra of Dodecadienic Compounds with a Conjugated Double Bond, Lepidopterous Sex Pheromones
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概要
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All geometrical isomers of 5, 7-, 6, 8-, 7, 9-, 8, 10- and 9, 11-dodecadien-1-ols, and their acetates and aldehyde derivatives were analyzed by electron impact mass spectrometry. The abundance of molecular ion (M+) was observed in every spectrum, and the relative intensity of M+ tended to be strong if the compound possessed an (E)-double bond(s). In addition to M+, [M -H2O] + (alcohols) and [M -CH3CO2H]+ (acetates), every dienic compound showed typical series of CnH2n-2+∼CnH2n-5+ with abundance maxima around C4, C5, C6 or C7. Each double bond positional isomer characteristically yielded different ion peaks in the series, which were useful for its distinction from other isomers. These results indicate that the chemical structure of a natural pheromone of Lepidoptera is easily deduced successfully by GC-MS analysis if it is a conjugated dienic pheromone.
- 社団法人 日本農芸化学会の論文
著者
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Ando T
Department Of Applied Biological Science Faculty Of Agriculture Tokyo University Of Agriculture And
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UCHIYAMA Masaaki
Department of Applied Biological Science, Faculty of Agriculture, Tokyo University of Agriculture an
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ANDO Tetsu
Department of Plant Protection, Faculty of Agriculture, Tokyo University of Agriculture and Technolo
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KATAGIRI Yoshio
Department of Plant Protection, Faculty of Agriculture, Tokyo University of Agriculture and Technolo
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Ando Tetsu
Department Of Agricultural Chemistry Faculty Of Agriculture The University Of Tokyo
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Uchiyama Masaaki
Department Of Agricultural Chemistry Faculty Of Agriculture University Of Tokyo
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