Synthesis of Fluorinated Pyrethroids : Conversion of Pyrethroid Metabolites into Some Insecticidal Fluorinated Derivatives
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概要
- 論文の詳細を見る
New fluorinated pyrethroids were designed to block microsomal oxidation at the C-10 methyl group of biophenothrin and at the C-7' methylene of bioallethrin. By using diethylaminosulfur trifluoride and/or hexafluoropropene diethylamine, 10,10-difluorobiophenothrin and 7'-fluorobioallethrin were synthesized from the oxidized derivatives of the parent insecticides, which have been recognized as microsomal metabolites. While 10-hydroxybiophenothrin was not successfully converted into the corresponding 10-fluoro derivative by either fluorination reagent, other monofluorinated compounds were formed and their structures were elucidated.
- 社団法人日本農芸化学会の論文
- 1992-10-23
著者
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ANDO Tetsu
Department of Plant Protection, Faculty of Agriculture, Tokyo University of Agriculture and Technolo
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Ando Tetsu
Department Of Agricultural Chemistry Faculty Of Agriculture The University Of Tokyo
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Ando Tetsu
Department Of Applied Biological Science Faculty Of Agriculture Tokyo University Of Agriculture And
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Matsuo Noritada
Takarazuka Research Center Sumitomo Chemical Co. Ltd.
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KOSEKI Nozomu
Department of Applied Biological Science, Faculty of Agriculture, Tokyo University of Agriculture an
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YASUHARA Isamu
Department of Applied Biological Science, Faculty of Agriculture, Tokyo University of Agriculture an
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ISHIWATARI Takao
Takarazuka Research Center, Sumitomo Chemical Co., Ltd.
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Koseki Nozomu
Department Of Applied Biological Science Faculty Of Agriculture Tokyo University Of Agriculture And
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Yasuhara Isamu
Department Of Applied Biological Science Faculty Of Agriculture Tokyo University Of Agriculture And
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Ishiwatari Takao
Takarazuka Research Center Sumitomo Chemical Co. Ltd.
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