Biosynthetic Pathway of Bombykol, the Sex Pheromone of the Female Silkworm Moth(Biological Chemistry)
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概要
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For investigation of the biosynthetic pathway of bombykol ((10E,12Z)-10,12-hexadecadien-1-ol, the female sex pheromone of the silkworm moth), some ^<14>C-labelled compounds were applied to pheromone glands of 1-day-old virgin female moths 4 hr after lighting (25〜27 hr after eclosion), and their incorporation into the pheromone was measured by the succeeding fractionation with normal-phase and reversed-phase TLC plates. [1-^<14>C](Z)-11-Hexadecenoic acid changed more easily to bombykol than [1-^<14>C]hexadecanoic acid, while [1-^<14>C](E)-11-hexadecenoic acid and [1-^<14>C] hexadecan-1-ol were scarcely incorporated into the pheromone. This result confirms the biosynthetic pathway via (Z)-11-hexadecenoate and (10E,12Z)-10,12-hexadecadienoate, which has been proposed by Yamaoka et al. and Bjostad and Roelofs. Some [1-^<14>C](Z)-11-hexadecen-1-ol was changed to bombykol, suggesting that the alcohol was oxidized to (Z)-11-hexadecenoic acid and this acid was taken into the biosynthetic pathway.
- 社団法人日本農芸化学会の論文
- 1988-02-23
著者
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Ando T
Department Of Applied Biological Science Faculty Of Agriculture Tokyo University Of Agriculture And
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Ando Tomoaki
Division Of Bioscience And Biotechnology Department Of Ecological Engineering Toyohashi University O
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ARIMA Rika
Department of Applied Biological Science, Faculty of Agriculture, Tokyo University of Agriculture an
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UCHIYAMA Masaaki
Department of Applied Biological Science, Faculty of Agriculture, Tokyo University of Agriculture an
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ANDO Tetsu
Department of Plant Protection, Faculty of Agriculture, Tokyo University of Agriculture and Technolo
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HASE Takema
Department of Plant Protection, Faculty of Agriculture, Tokyo University of Agriculture and Technolo
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Ando T
Graduate School Of Bio-applications And Systems Engineering (base) Tokyo University Of Agriculture A
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Arima Rika
Department Of Applied Biological Science Faculty Of Agriculture Tokyo University Of Agriculture And
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Ando Tetsu
Department Of Agricultural Chemistry Faculty Of Agriculture The University Of Tokyo
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Hase Takema
Department Of Plant Protection Faculty Of Agriculture Tokyo University Of Agriculture And Technology
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Uchiyama M
Department Of Applied Biological Science Faculty Of Agriculture Tokyo University Of Agriculture And
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Uchiyama M
Department Of Plant Protection Faculty Of Agriculture Tokyo University Of Agriculture And Technology
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Uchiyama Masaaki
Department Of Agricultural Chemistry Faculty Of Agriculture University Of Tokyo
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