COOXIDATION OF ENONES DURING REACTION OF SUPEROXIDE WITH ACIDIC AROMATIC AMINES
スポンサーリンク
概要
- 論文の詳細を見る
Enones can be epoxidized by O_2^<-・> in the presence of various compounds having an acidic >NH group. Cyclic voltammetry and ESR study show that O_2^<-・> was disproportionated into H_2O_2 and O_2 by these compounds. Furthermore, H_2O_2 was deprotonated by unreacted O_2^<-・> and HOO^- was formed, which is widely known to be the effective oxidant in the epoxidation of enones. This confirms the strong basicity of O_2^<-・> in aprotic media, and we propose an alternative scheme for the Haber-Weiss reaction in the absence of metal ions.
- 公益社団法人日本薬学会の論文
- 1991-07-25
著者
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長野 哲雄
Faculty of Pharmaceutical Sciences, University of Tokyo
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広部 雅昭
Faculty of Pharmaceutical Sciences, University of Tokyo
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滝沢 博正
Faculty of Pharmaceutical Sciences, University of Tokyo
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広部 雅昭
Faculty Of Pharmaceutical Sciences University Of Tokyo
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広部 雅昭
東京大学薬学部:文部省
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滝沢 博正
Faculty Of Pharmaceutical Sciences University Of Tokyo
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