Studies on Photochemical Reactions of Air Pollutants. VIII. Photochemical Epoxidation of Olefins with NO_2 in a Solid-Gas Phase System

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概要

• 論文の詳細を見る

• Upon irradiation with a xenon lamp through a Pyrex filter (cut-off below 290 nm), olefinic compounds such as trans-stilbene, cyclohexene, 4,5-dibromocyclohexene and aldrin reacted with nitrogen dioxide, an air pollutant which induces photochemical smog, in air and gave the corresponding epoxides in good yields, while phenanthrene gave 9,10-phenanthrenequinone and 9-hydroxy-10-nitrophenanthrene. Furthermore, the photochemical and dark reactions of phenanthrene 9,10-oxide with nitrogen dioxide in air both resulted in the same products as above. Therefore, phenanthrene 9,10-oxide seems to be an intermediate in the photochemical reaction of phenanthrene with nitrogen dioxide in air.

• 公益社団法人日本薬学会の論文
• 1982-12-25

著者

• 広部 雅昭

  Faculty of Pharmaceutical Sciences, University of Tokyo

• 大谷 武司

  城西大学

• 菅野 三郎

  Faculty Of Pharmaceutical Sciences Josai University

• 大谷 武司

  Faculty of Pharmaceutical Sciences, Chiba University

• 広部 雅昭

  Faculty Of Pharmaceutical Sciences University Of Tokyo

• 野島 一宏

  Faculty of Pharmaceutical Sciences, Josai University

• 野島 一宏

  Faculty Of Pharmaceutical Sciences Josai University

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