Clusters [Fe_4S_4(SR)_4]^<2-> as Novel Catalysts in Organic Reductions
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概要
- 論文の詳細を見る
The cluster [Fe_4S_4(SR)_4]^<2-> catalyzed the reductions of nitro compunds, quinones and N-oxide compounds to amines, hydroquinones, and deoxygenated compounds, respectively, in the presence of thiols in CH_3CN solution. The reaction mechanism was also investigated by electron spin resonance spectroscopy, and it was concluded that these reactions proceed via one-electron transfer from the cluster to the substrates.
- 社団法人日本薬学会の論文
- 1986-05-25
著者
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長野 哲雄
Faculty of Pharmaceutical Sciences, University of Tokyo
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広部 雅昭
Faculty of Pharmaceutical Sciences, University of Tokyo
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伊藤 喬
Faculty Of Pharmaceutical Sciences University Of Tokyo
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広部 雅昭
Faculty Of Pharmaceutical Sciences University Of Tokyo
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広部 雅昭
東京大学薬学部:文部省
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