Formation of Cyanide Ion or Cyanogen Chloride through the Cleavage of Aromatic Rings by Nitrous Acid or Chlorine. VI. Evidence for Ring Cleavage of Benzene and Aniline
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It was found that aniline [^<13>C_6] reacted with nitrous acid to give ^<13>CN^- and that benzene [^<13>C_6] or aniline [^<13>C_6] reacted with hypochlorous acid in the presence of ammonium ion to give ^<13>CNCl. These results clearly indicate that the benzene ring was cleaved by nitrous acid or chloramine to give cyanide ion or cyanogen chloride.
- 公益社団法人日本薬学会の論文
- 1984-01-25
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