Electron Paramagnetic Resonance of Gd^<3+> Centres in Rb_2CdF_4 and Cs_2CdF_4 Crystals
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概要
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EPR measurements on three kinds of Gd" centres in Rb.CdF. and Cs.CdF.crystals co-doped with Li" and Na" ions have been made at room temperatures. Forthe Cd"-vacancy associated centre and the Li"-associated centre, the fine structureterms with orthorhombic symmetry have been separated into uniaxial terms about thecrystalline c and b axes and cubic terms. The separated axial parameters have beencompared with the axial parameters for the uncompensated centres in the samecrystals and the corresponding tetragonal centres in the perovskite crystals. The expressions for the parameters derived by the separation of spitt-l-Iamiltonian terms arecoincident with those derived by the superposition model for the local environmentsof Gd" ions with radial deviation of ligands. The relation of the separation methodto the Rudowicz's net charge compensation model has been shown.
- 社団法人日本物理学会の論文
- 1987-12-15
著者
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竹内 秀夫
Department Of Information Electronics School Of Engineering Nagoya University
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EBISU Hiroshi
Department of Electrical and Computer Engineering, Nagoya Institute of Technology
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Ebisu H
Department Of Physics Nagoya Institute Of Technology
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Ebisu Hiroshi
Department Of Electrical And Computer Engineering Nagoya Institute Of Technology
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Arakawa Masanori
Department of Physics, Nagoya Institute of Technology
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Takeuchi Hideo
Department of Information Electronics, School of Engineering, Nagoya University
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Tamai Hiroshi
Department Of Fusion Plasma Research Japan Atomic Energy Research Institute
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Takeuchi Hideo
Department Of Applied Physics Faculty Of Engineering Osaka City University
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Tamai H
Japan Atomic Energy Research Inst. Ibaraki Jpn
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Arakawa M
Sophia Univ. Tokyo
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Arakawa Masanori
Department Of Physics Faculty Of Science Nagoya University
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Arakawa Mitsuyoshi
Department Of Physics Sophia University
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Takeuchi Hiroshi
Division Of Thermonuclear Fusion Research Japan Atomic Energy Research Institute Tokai Establishment
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