EPR Study of Monoclinic Centres in CsCdF_3 and CsCaF_3 Co-Doped with Gd^<3+> and Na^+ Ions
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概要
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EPR measurements have been made on single crystals of CsCdF_3 and CsCaF_3 codoped with Gd^<3+> and Na^+ using X-band spectrometer. A new weak spectrum with monoclinic symmetry is observed. The principal z-axis is deviated about 8°for CsCdF_3 and 6°for CsCaF_3 from the crystalline axis in a <100> direction. The new centre is ascribed to a Gd^<3+>ion associated with a Na^+ ion at the nearest divalent cation site. Its intervening F^- ion is considered to be displaced from the face centre point toward a <110> direction normal to the Gd^<3+>-Na^+ pair axis. The out-of-axis displacement shows that the intervening F^- ion on the pair axis becomes unstable by the existence of the associated Na^+ ion.
- 社団法人日本物理学会の論文
- 1995-04-15
著者
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竹内 秀夫
Department Of Information Electronics School Of Engineering Nagoya University
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EBISU Hiroshi
Department of Electrical and Computer Engineering, Nagoya Institute of Technology
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Ebisu H
Department Of Physics Nagoya Institute Of Technology
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Ebisu Hiroshi
Department Of Electrical And Computer Engineering Nagoya Institute Of Technology
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Arakawa Masanori
Department of Physics, Nagoya Institute of Technology
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Takeuchi Hideo
Department of Information Electronics, School of Engineering, Nagoya University
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Tamai Hiroshi
Department Of Fusion Plasma Research Japan Atomic Energy Research Institute
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Takeuchi Hideo
Department Of Applied Physics Faculty Of Engineering Osaka City University
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Tamai H
Japan Atomic Energy Research Inst. Ibaraki Jpn
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Arakawa M
Sophia Univ. Tokyo
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Arakawa Masanori
Department Of Physics Faculty Of Science Nagoya University
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Arakawa Mitsuyoshi
Department Of Physics Sophia University
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Takeuchi Hiroshi
Division Of Thermonuclear Fusion Research Japan Atomic Energy Research Institute Tokai Establishment
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