Note on Isotope Effect in Hydrogen Bonded Crystals
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概要
- 論文の詳細を見る
By making use of a simple model potential for hydrogen bond, empirical relation between oxygen-oxygen distance and oxygen-hydrogen distance found widely in various hydrogen bonded crystals is explained. It is pointed out that, between theoretical prediction and observed empirical data, there exists a salient discrepancy which is to be resolved by considering quantum effect or tunneling motion of hydrogen atom. the tunneling effect is treated by a variational method on a one dimensional model of hydrogen bond. Possibility of isotope effect in hydrogen bond length is examined and some speculation is given on a new interpretation of the isotope effect in ferro or antiferroelectric phase transition temperatures in hydrogen bonded crystals.
- 理論物理学刊行会の論文
- 1982-01-25
著者
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MATSUBARA Takahiko
Department of Physics and Astronomy, The Johns Hopkins University
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MATSUBARA Takeo
Department of Physics, Kyoto University
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MATSUBARA Takeo
ICMT
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Matsushita Eiko
Department Of Physics Kyoto University
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Matsubara Takeo
Department Of Applied Physics Okayama University Of Science
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MATSUBARA Takeo
Department of Applied Physics, Okayama University of Science
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