Heterogeneous photosensitized oxygenation of 2,3-dimethyl-2-butene.
スポンサーリンク
概要
- 論文の詳細を見る
Photo-oxygenation of 2,3-dimethyl-2-butene was performed using dye-supported solid particles as photosensitizer. Quantitative effects of solid sensitizer concentration and of dye quantity supported on solid particles were investigated. The light absorption rate in the heterogeneous system was assessed by a Monte Carlo simulation. The reaction rate was proportional to the <I>n</I>-th order of light absorption rate, where <I>n</I> was a little less than unity, and to the 0-th order of butene concentration in a feed range of 5 × 10<SUP>1</SUP>–2 × 10<SUP>2</SUP> mol/m<SUP>3</SUP>. The rate constant was a function of dye quantity supported on solid particles. This is due to the adsorbate–adsorbate interaction.
- The Society of Chemical Engineers, Japanの論文
著者
-
Takahata Yasuyuki
Department Of Chemistry And Chemical Engineering Faculty Of Engineering Yamagata University
-
Yokota Toshiyuki
Department Of Chemistry And Chemical Engineering Faculty Of Engineering Yamagata University
-
Suzuki Keiichi
Department Of Animal Breeding And Genetics Graduate School Of Agricultural Science Tohoku University
-
TAKAHASHI Koji
Departent of Materials Science and Engineering,Faculty of Engineering,Yamagata University
-
Hosoya Jun
Department of Chemical Engineering, Yamagata University
-
Suzuki Keiichi
Department of Chemical Engineering, Yamagata University
関連論文
- Five cases of thrombocytopenia induced by primary human herpesvirus 6 infection
- The Influence of the Bottom Shape of an Agitated Vessel Stirred by Dual Impellers on the Distribution of Solid Concentration
- Substrate Specificities of Deuterolysin from Aspergillus oryzae and Electron Paramagnetic Resonance Measurement of Cobalt-substituted Deuterolysin(Biochemistry & Molecular Biology)
- Bubble Size Distribution near the Vessel Wall in a Gas Sparged Vessel Agitated by Pitched Blade Paddle Up-Pumping
- Soluble Egg Shell Membrane Protein as a Regulating Material for Collagen Matrix Reconstruction
- The Influence of Platelets on the Promotion of Invasion by Tumor Cells and Inhibition by Antiplatelet Agents
- Investigation of New Embedding Mediums for Cytochemistry and Immunoelectronmicroscopy.
- RELATION BETWEEN IMPACT VELOCITY OF PARTICLE AND SIZE OF CRATER FORMED ON SOFT SURFACE
- A case of averrant thyroid carcinoma connected with the thyroid by a fibrous band
- D315 A NOVEL FLUIDIC MICROMOTOR DRIVEN BY THERMOCAPILLARY FORCE(Micro-scale phenomena)
- Mixing Time for Different Diameters of Impeller at a High Solid Concentration in an Agitated Vessel
- GI-10 EVALUATION METHOD OF GEAR MEASURING INSTRUMENT USING V-GROOVE ARTIFACT(INSPECTION OF GEARS)
- GI-08 EVALUATION OF GEAR MEASURING INSTRUMENT USING MULTIPLE-TOOTH INVOLUTE HELICOID ARTIFACT(INSPECTION OF GEARS)
- Coloured Petri Net Based Modelling and Analysis of Multiple Product FMS with Resource Breakdowns and Automated Inspection(Concurrent Systems)
- The Modeling and analysis of Guide-path configurations of an integrated Automated guided Vehicle system using Colored Petri Net
- Hierarchical Control Modeling of Automated Guided Vehicle System (AGVS) using Colored Petri Net
- Colored Petri Net based Performance analysis of Flexible Manufacturing System with planned and unplanned Resource Breakdowns
- Colored Petri Net based Performance analysis of Flexible Manufacturing System with planned and unplanned Resource Breakdowns
- Effect of Sorbed Water on the Thermal Stability of Soybean Protein
- Improved Physical and Biochemical Features of a Collagen Membrane by Conjugating with Soluble Egg Shell Membrane Protein
- Contribution of the Net Charge to the Regulatory Effects of Amino Acids and ε-Poly(L-lysine) on the Gelatinization Behavior of Potato Starch Granules
- Interfacial Behavior of Fatty-Acylated Sericin Prepared by Lipase-Catalyzed Solid-Phase Synthesis
- Thermal Behavior of Fowl Feather Keratin
- Stable,Single-Mode Oscillation with High-Order Volume Mode at 1MW,170GHz Gyrotron
- Numerical Simulation of the Flow Field in the Mixing Section of a Screw Extruder by the Lattice Gas Automata Method
- Synthesis and Characterization of Ba β-Diketonate Cormplexes for Chemical Vapor Deposition of Thin-Film Superconductors
- Freeze-Drying of Copper-Oxide-Based Porous Bulk Catalysts for Diesel Soot Combustion
- Processing of Porous Metal Oxide Particles for Combustion Catalysis by Freeze-drying
- A Growth Kinetics Model of Euglena gracilis in Fed-batch Mixotrophic Culture
- Hepatocellular carcinoma with extensive peliotic change
- Gassed Power Consumption and Gas Hold-up for a Dual Hollow Blade Impeller System in a Stirred Vessel
- Gas Dispersion Characteristics of Newly Developed Impellers in a Stirred Vessel
- A Novel Measurement Technique for Mixing Time in an Aerated Stirred Vessel
- Voltammetric Response of a γ-Irradiated Poly(N-vinylcaprolactam)Modified Graphite Electrode to Catechol and Ascorbic Acid
- Effects of Frequency on the Crack-Healing Behavior of Si_3N_4/SiC Composite under Cyclic Stress(Macro-, Micro-, Meso-, and Nano-scopic Strength of Materials Relating to Microstructures)
- Serotonin-immunoreactive Epithelial Cells in the Main Excretory Ducts of Rat Submandibular Glands
- Evaluation of the Usefulness of Percutaneous Transhepatic Portal Catheterization for Preoperatively Diagnosing the Localization of Insulinomas
- Microheater-Driven Dancing Microbubble
- Mixing Performance Experiments in an Agitated Vessel Equipped with a Pitched Paddle Subjected to Unsteady Agitation
- Abrasion of Particle by Small Impeller in an Agitated Vessel
- Functional Changes of Lysozyme by Conjugating with Carboxymethyl Dextran
- Control of Crystal Size Distributions in a Seeded Batch Crystallizer
- EFFECT OF SCALE ON PARTICLE-IMPELLER IMPACT IN AN AGITATED VESSEL EQUIPPED WITH A RUSHTON TURBINE
- PARTICLE-IMPELLER IMPACT IN AN AGITATED VESSEL EQUIPPED WITH A RUSHTON TURBINE
- Increased Hydrophobicity of Carboxymethyl Starch Film by Conjugation with Zein(Food & Nutrition Science)
- Collisional Evolution of Galaxy Clusters and the Growth of Common Halos
- Gas-Liquid Mass Transfer Coefficient of a Pitched Bladed Paddle Up-Pumping at Extraordinary Large Gas Flow Rates
- Anisotropic Scattering Model for Estimation of Light Absorption Rates in Photoreactor with Heterogeneous Medium
- Development of an Aerobic Cultivation System by Using a Microbubble Aeration Technology
- Theoretical Tool for Optimum Design of Mixer, and Visualization and Quantification of Mixing Performance
- Increase of cytochrome c oxidase negative fibers in rimmed vacuole myopathy with inflammatory changes
- Laminar Mixing in Eccentric Stirred Tank with Different Bottom
- Lactic Acid Fermentation from Rice by Adopting Food Wastes as Nutrients
- Polymerized Structure and Improved Physical and Biochemical Material Properties of Carboxymethyl Dextran-Conjugated Collagen
- Soft Textural and Emulsifiable Gelatin Formed by Conjugating with Fatty-Acylated Saccharide
- Reversible Thermal Transition of Soluble Branched Chains from Slightly Acid-treated Potato Starch
- Mediastinal lymphatic drainage from pulmonary lobe based on CT observations of histoplasmosis : implications for minimal N2 disease of non-small-cell lung cancer
- Study on the Changes of the Nucleic Acids Content of the Liver and Kidney during Compensatory Growth of the Mice Selected for Resistance to Starvation
- Improvement of the Physical Properties of Pepsin-Solubilized Elastin-Collagen Film by Crosslinking
- Development of a Lactic Acid Recovery System Using Ammonia from a Fermentation Broth
- Liquefaction for the Lactic Acid Fermentation from Rice
- Flow in a Poppet Valve : Computation of Pressure Distribution using a Streamline Coordinate System
- Effects of GH gene polymorphism and sex on carcass traits and fatty acid compositions in Japanese Black cattle
- DEVELOPMENT AND MIXING CHARACTERISTICS OF FOLDING ANCHOR IMPELLER FOR ROUND-BOTTOMED FLASK
- PARTICLE-IMPELLER IMPACT FOR A SIX BLADED 45°PITCHED TURBINE IN AN AGITATED VESSEL
- EFFECT OF PARTICLE-IMPELLER IMPACT RATE ON PROPERTIES OF PRODUCT CRYSTALS IN AGITATED CRYSTALLIZERS OF DIFFERENT SIZES
- Structural Characterization of the Gene for Human Histidine-Rich Glycoprotein, Reinvestigation of the 5'-Terminal Region of cDNA and a Search for the Liver Specific Promoter in the Gene
- Numerical Processing of a Visualized Streak Line Image using a Streamline Coordinate System
- Fabrication of a Microevaporator Equipped with a Piezoelectrically-Driven Diaphragm Pump
- A NEW GROWTH KINETIC MODEL FOR PHOTO-AUTOTROPHIC MICROALGAE CULTURE
- Mass Transfer Characteristics by Surface Aeration of Large Paddle Impeller : Application to a Polymerization Reactor with Liquid Level Change
- Numerical Analysis of an Axisymmetric Jet Using a Streamline Coordinate System
- EFFECT OF SIZE OF SPHERICAL PARTICLE ON COMPLETE SUSPENSION SPEED IN AGITATED VESSELS OF DIFFERENT SCALE
- A STUDY OF THE AGITATION SPEED TO JUST CAUSE COMPLETE SUSPENSION FOR NON-SPHERICAL PARTICLES
- Development of a Simulator for the Fuel Injecton Sysem of a Diesel Engine
- Biotransformation of Isoflavones by the Larvae of the Common Cutworm (Spodoptera litura)
- MIXING OF HIGHLY VISCOUS NEWTONIAN LIQUID IN A HELICAL RIBBON AGITATED VESSEL AT VARIOUS LIQUID DEPTHS
- Control of Collagen Molecular Assembly with Anionic Polysaccharides
- Distribution of Solid Particles Lighter than Liquid in an Agitated Vessel Stirred by Dual Impellers
- 酢酸セルロース-ジルコニア複合ゲル繊維へのウレアーゼの包括固定化
- Functional Changes of Carboxymethyl Potato Starch by Conjugating with Amino Acids
- Contribution of Charged Amino Acids to Improving the Degraded Viscosity of Potato Starch Paste by a Retort Treatment and during Storage
- Endowed Multi-functionality of Branched Oligosaccharide from Corn Starch by Phosphorylation and Oleylation
- Chaotic Mixing in a Vessel Agitated by Large Impeller
- Regulation of Collagen Matrix Reconstruction by Phosphated Polysaccharides
- Prediction of the Laminar Two-Dimensional Jet Flow through a Convergent Channel
- β-Lactoglobulin Protects β-Ionone Related Compounds from Degradation by Heating,Oxidation, and Irradiation
- ULTRASONIC MEASUREMENT OF LOCAL CONCENTRATION OF CAKE ON MICROFILTRATION MEMBRANE USING POLYMER TRANSDUCER
- Minimum Impeller Speeds for Complete Liquid-Liquid Dispersion in a Baffled Vessel
- Preparation of Silica Microcapsules by Sol-Gel Method in W/O Emulsion
- Preparation of Methylene Blue-Silica Composite Microcapsules
- Evaluation of genetic trends and determination of the optimal number of cumulative records of parity required in reproductive traits in a Large White pig population
- Application of gel filtration chromatography for monitoring cellulase production from Trichoderma viride.
- Circulation time for pseudoplastic liquids in a vessel equipped with a variety of helical ribbon impellers.
- Measurement of cake thickness on membrane for microfiltration of yeast using ultrasonic polymer concave transducer.
- FEEDFORWARD CONTROL OF MULTISTAGE PROCESS
- Heterogeneous photosensitized oxygenation of 2,3-dimethyl-2-butene.
- ESTIMATION OF LIGHT ABSORPTION RATE IN A TANK TYPE PHOTOREACTOR WITH MULTIPLE LAMPS INSIDE
- Cake formation and spatial partitioning in batch microfiltration of yeast.
- A new random-walk model for assessment of light energy absorption by a photosynthetic microorganism.