Structural and Optical Properties of In-Plane Ordered Metallo-Phthalocyanine Thin Films Formed on Sapphire by Organic Molecular Beam Deposition
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概要
- 論文の詳細を見る
Thin films of dibenzo [b, t] phthalocyaninato-Zn (II) (ZnDBPc) were grown by UHV molecular beam deposition on polished sapphire (1^^-012) surfaces. The structural and optical properties of the ZnDBPc films were investigated by atomic force microscopy, X-ray diffraction, polarization spectroscopy, and optical third harmonic generation. The films showed in-plane ordering over the entire substrate. Equally spaced atomic step arrays were clearly observed on the polished sapphire (1^^-012) surface. The ZnDBPc molecules stacked themselves to form molecular columns, and the stacking direction was parallel to the step direction, resulting in in-plane ordering of the ZnDBPc films. The ordered ZnDBPc film strongly promoted the ordering of a TiOPc thin film deposited on it. The third-order nonlinear optical susceptibility X of this ordered TiOPc/ZnDBPc double-layer film showed high anisotropy, and its maximum X value was 3.0×10^<-10> esu.
- 社団法人応用物理学会の論文
- 1995-07-30
著者
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林 卓
Department Of Materials Science Shonan Institute Of Technology
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Foelsch S
Freie Univ. Berlin Berlin Deu
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Yamashita A
Tokai Univ. Hiratsuka Jpn
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HAYASHI Takayoshi
NTT Integrated Information & Energy Systems Laboratories
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Hayashi Takafumi
Department Of Applied Physics Faculty Of Engineering The University Of Tokyo
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Hayashi Takayoshi
Advanced Research Institute For Science And Engineering Waseda University
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Maruno T
Ntt Photonics Laboratories Ntt Corporation
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Matsuura Tohru
Ntt Photonics Laboratories Ntt Corporation
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Kanbara Hirohisa
NTT Opto-electronics Laboratories
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Yamashita A
Ntt Interdisciplinary Research Laboratories
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MARUNO Tohru
NTT Interdisciplinary Research Laboratories
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YAMASHITA Akira
NTT Interdisciplinary Research Laboratories
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FOLSCH Stefan
NTT Interdisciplinary Research Laboratories
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KONAMI Hideo
Institute for Chemical Reaction Science, Tohoku University
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HATANO Masahiro
Institute for Chemical Reaction Science, Tohoku University
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Kanbara H
Institute For Chemical Reaction Science Tohoku University
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Kanbara Hirohisa
Ntt Optoelectronics Laboratories
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Hatano M
Institute For Chemical Reaction Science Tohoku University
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Hatano Masahiro
Institute For Chemical Reaction Science
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Konami Hideo
Institute For Chemical Reaction Science
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