Fabrication and Properties of (Bi,La)4Ti3O12 Thin Films through Metal-Organic Compounds (特集 高精度電子部品材料)

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概要

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• (Bi,La)4Ti3O12 thin films of Bi-layered perovskite structure were fabricated on Pt/TiOx/SiO2/Si substrates by chemical solution deposition (CSD) method. The crystallization and microstructure of the (Bi,La)4Ti3O12 thin films markedly depended upon the kind of used La-sources when the precursor solutions were prepared. Synthesized Bi3.35La0.75Ti3O12 (BLT) thin films from the precursor solution using a La(OiPr)3 as a starting material revealed (00l ) preferred orientation and anisotropic grain growth. On the other hand, BLT thin films using a La(OAc)3 as a La-source showed random orientation with a strong (117) reflection and homogeneous microstructure. This is due to the difference in the pyrolysis and crystallization behaviors of the precursor films. The BLT thin films exhibited the well-saturated ferroelectric P-E hysteresis loops. The BLT thin film prepared from a La-acetate showed the Pr value of 15.6 μC/cm2, which was higher than that of the BLT thin films from a La-alkoxide.

• 社団法人粉体粉末冶金協会の論文
• 2005-12-15

著者

• 余語 利信

  Division Of Nanomaterials Science Ecotopia Science Institute Nagoya University

• Yogo Toshinobu

  Ecotopia Science Institute Nagoya University

• 坂本 渉

  Division Of Nanomaterials Science Ecotopia Science Institute Nagoya University

• HIRANO Shin-ichi

  Department of Applied Chemistry, Graduate School of Engineering, Nagoya University

• SAKAMOTO Wataru

  EcoTopia Science Institute, Nagoya University

• MIZUTANI Yu-ki

  EcoTopia Science Institute, Nagoya University

• YAMADA Mio

  Department of Applied Chemistry, Graduate School of Engineering, Nagoya University

• IIZAWA Naoya

  Department of Materials Science, Shonan Institute of Technology

• TOGAWA Daichi

  Department of Materials Science, Shonan Institute of Technology

• HAYASHI Takashi

  Department of Materials Science, Shonan Institute of Technology

• MIZUTANI Yu-ki

  Center for Integrated Research in Science and Engineering, Nagoya University

• Iizawa Naoya

  Department Of Materials Science Shonan Institute Of Technology

• Yamada M

  Department Of Applied Chemistry Graduate School Of Engineering Nagoya University

• Yamada Mio

  Department Of Applied Chemistry Graduate School Of Engineering Nagoya University

• Mizutani Yu-ki

  Ecotopia Science Institute Nagoya University

• Hirano S

  Division Of Nanomaterials Science Ecotopia Science Institute Nagoya University

• 林 卓

  Department Of Materials Science Shonan Institute Of Technology

• 坂本 渉

  呉工業高等専門学校

• Iizawa Naoya

  Department Of Materials Science And Engineering Shonan Institute Of Technology

• Togawa D

  Shonan Inst. Technol. Kanagawa Jpn

• Togawa Daichi

  Department Of Materials Science And Engineering Shonan Institute Of Technology

• Hayashi T

  Research Laboratory Oki Electric Industry Co. Ltd.

• Hirano Shi-ichi

  Department Of Applied Chemistry Graduate School Of Engineering Nagoya University

• Hayashi T

  Nisshin Electric Co.

• Hayashi Tsukasa

  R D Division Nissin Electric Co. Ltd.

• Sakamoto Wataru

  Res. Inst. Bioresources Okayama Univ.

• Sakamoto Wataru

  Division Of Applied Biosciences Graduate School Of Agriculture Kyoto University

• Sakamoto Wataru

  Faculty Of Agriculture Kyoto University

• Hayashi Takahisa

  Vlsi Research & Development Center Oki Electric Industry Co Ltd.

• Hayashi Takafumi

  Department Of Applied Physics Faculty Of Engineering The University Of Tokyo

• Hirano Shin‐ichi

  Division Of Nanomaterials Science Ecotopia Science Institute Nagoya University

• Hirano Shin-ichi

  Central Research Laboratories Mercian Corp.

• Hirano Shin-ichi

  Department Of Applied Chemistry Graduate School Of Engineering Nagoya University

• Hayashi Toshiyuki

  Department Of Mechanical Engineering Nagoya University

• Hayashi Takayoshi

  Advanced Research Institute For Science And Engineering Waseda University

• Hayashi Takayoshi

  Musashino Electrical Communication Laboratory Nippon Telegraph And Telephone Public Corporation

• 林 卓

  マテリアル工学科

• Mizutani Y

  Ecotopia Science Institute Nagoya University

• Sakamoto W

  Research Institute For Bioresources Okayama University

• Hirano S

  Central Research Laboratories Mercian Corp.

• Hirano Shin-ichi

  Environmental Research Center Mercian Cleantec Corporation

• HAYASHI Teru

  Research Laboratory of Precision Machinery and Electronics,Tokyo Institute of Technology

• Hayashi Takashi

  Department Of Applied Chemistry Graduate School Of Engineering Osaka University

• Sakamoto Wataru

  Ecotopia Science Institute And Department Of Molecular Design And Engineering Graduate School Of Eng

• Sakamoto Wataru

  Research Institute For Bioresources Kurashiki University

• Iizawa Naoya

  Department of Material Science and Engineering, Shonan Institute of Technology

• Hirano Shin-ichi

  Department of Material and Life Science, Graduate School of Engineering, Osaka University

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