A New Reductone derived from D-Glucuronolactone by Alkali. I. Isolation of 3-Keto-4,5-dideoxy-trans-4,5-dehydro-glucuronic Acid
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概要
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An aqueous solution of D-glucuronolactone (I) produces a yellow color by alkali. This yellow substance (II) was isolated from the precipitates obtained by treating I in dimethylformamide with potassium hydroxide in methanol at 70°. It had a strong reducing character, indicating the presence of oxo-ene-diol grouping in the molecule, and gave fumaric acid (VI) and 4-oxo-glutaconic acid (IV) on periodic acid oxidation. The structure of 3-keto-4,5-dideoxy-trans-4,5-dehydro-glucuronic acid was proposed to this new reductone.
- 公益社団法人日本薬学会の論文
- 1970-01-25
著者
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木村 道也
Faculty of Pharmaceutical Sciences, Hokkaido University
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神力 就子
Faculty of Pharmaceutical Sciences, School of Medicine, Hokkaido University
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河田 明治
The National Institute For Environmental Studies
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河田 明治
Faculty of Pharmaceutical Sciences, Hokkaido University
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石舘 守三
Faculty of Pharmaceutical Sciences, University of Tokyo
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石舘 守三
Faculty Of Pharmaceutical Sciences Hokkaido University
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神力 就子
Faculty Of Pharmaceutical Sciences Hokkaido University
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水谷 由紀子
Faculty of Pharmaceutical Sciences, Hokkaido University
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木村 道也
Faculty Of Pharmaceutical Sciences Hokkaido University
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水谷 由紀子
Faculty Of Pharmaceutical Sciences Hokkaido University
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