The Sulfone Stretching Frequencies of Some Phenylsulfonyl Derivatives.
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概要
- 論文の詳細を見る
Infrared spectra of 48 kinds of phenylsulfonyl derivatives were measured and the substituent influence on the SO_2 stretching frequency was discussed in terms of electronic effects. In each series of homolog of phenyl 2-chloroethyl sulfone, 2-mesyloxyethyl sulfone, vinyl sulfone, and ethyl sulfone, the linear correlation of v_<as> with Hammett's σ of p-substituent was recognized. It was also observed that β-substituents such as chloro- and mesyloxy- exert a certain degree of effect on the frequency shift, respectively. The SO_2 stretching vibration of phenyl vinyl sulfone derivatives appeared in somewhat upward wave number compared with that of phenyl ethyl sulfone series.
- 社団法人日本薬学会の論文
- 1963-02-25
著者
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神力 就子
北海道工開試
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神力 就子
工技院北海道工業開発試験所
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神力 就子
Faculty of Pharmaceutical Sciences, School of Medicine, Hokkaido University
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南原 利夫
Faculty of Pharmaceutical Sciences, School of Medicine, Hokkaido University
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神力 就子
Faculty Of Pharmaceutical Sciences Hokkaido University
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