フェニルスルホン類のポーラログラフィー
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概要
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Polarography of 16 phenylsulfonyl derivatives having vinyl, ethyl, or 2-chloroethyl group attached directly to SO_2 group was carried out vs. mercury pool in benzene-methanol (3 : 2,v/v) solution using tetrabutylammonium iodide (0.08M) as a supporting electrolyte. The reduction waves observed with these compounds were classified into three types ; waves due to vinyl group (W_V), to phenylsulfonyl group (W_P), and to p-substituted halogen (W_X). Both W_V and W_P seemed to be irreversible, and the half-wave reduction potential (E_<1/2>) of the former was found to be ca. -1.5 V (two-electron reduction), while that of the latter was ca. -1.4--1.9V. W_X appeared at the most positive potential among the three reduction waves. Some discussions were made on the relationship between the structure and E_<1/2>.
- 社団法人日本薬学会の論文
- 1969-10-25
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