Studies on the Reaction between Polynitrobenzene Compounds and Active Methylene Group. XI. Kinetic Study on the Janovsky Reaction of Trinitrobenzene with Cyclohexanone in Methanol
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概要
- 論文の詳細を見る
The Janovsky reaction of 1,3,5-trinitrobenzene with cyclohexanone was studied kinetically. The rate-determining step is the addition of cyclohexanonate anion to trinitrobenzene. Kinetic and thermodynamic parameters are compared with those of the reaction with acetone. And the mechanism of the Zimmermann reaction of m-dinitrobenzene is suggested.
- 公益社団法人日本薬学会の論文
- 1973-02-25
著者
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木村 道也
Faculty Of Pharmaceutical Sciences Hokkaido University
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小尾 陞
Faculty of Pharmaceutical Sciences, University of Hokkaido
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柿崎 弘子
Faculty of Pharmaceutical Sciences, Hokkaido University
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柿崎 弘子
Faculty Of Pharmaceutical Sciences Hokkaido University
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小尾 陞
Faculty Of Pharmaceutical Sciences Hokkaido University
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