On the Oxygenation of Several Aromatic and Aliphatic Compounds with Aqueous Ferrous Ion-molecular Oxygen

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概要

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• Hydroxylation was shown to occur readily in the reactions of aromatic compounds such as benzoic acid, nitrobenzene, acetanilide, and phenol with ferrous ion-molecular oxygen in 0.5 M phosphate buffer (pH 6.8) at 40℃ for 3 h. The yields of hydroxylated products were higher than those obtained with other reported hydroxylation systems of transition metalmolecular oxygen. The NIH shift was not observed in the title reactions of C (4)-deuterioacetanilide and C (4)-deuteriobenzoic acid. This system was also demonstrated to oxygenate caproic acid to give a mixture of 3-, 4-, and 5-oxocaproic acids in 67% total yield.

• 社団法人日本薬学会の論文
• 1983-01-25

著者

• 柴田 邦彦

  Faculty Of Pharmaceutical Sciences Hokkaido University

• 三浦 敏明

  Faculty Of Pharmaceutical Sciences Hokkaido University

• 木村 道也

  Faculty of Pharmaceutical Sciences, Hokkaido University

• 安達 健一

  Faculty of Pharmaceutical Sciences, Hokkaido University

• 澤谷 拓治

  Faculty of Pharmaceutical Sciences, Hokkaido University

• 沢谷 拓治

  Faculty of Pharmaceutical Sciences, Hokkaido University

• 安達 健一

  Faculty Of Pharmaceutical Sciences Hokkaido University

• 沢谷 拓治

  北海道大学 薬

• 澤谷 拓治

  Faculty Of Pharmaceutical Sciences Hokkaido University

• 木村 道也

  Faculty Of Pharmaceutical Sciences Hokkaido University

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