On the Mode of Oxygenation with the Ferric Perchlorate-Hydrogen Peroxide System
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概要
- 論文の詳細を見る
The reactions of three kinds of substrates with hydrogen peroxide catalyzed by ferric perchlorate in acetonitrile were investigated and compared with those occurring in the Fe (acac)_3/alkylhydroperoxide system, which are governed by a radical process. Allylic oxidation and epoxidation both proceeded in the reaction of cholesteryl acetate, and the α-stereoselectivity of the epoxidation was enhanced by the presence of a radical scavenger. In the reactions of cis-and trans-stilbenes, stereospecific epoxidation by a non-radical process occurred, as well as a non-stereospecific reaction. The third substrate, adamantane, was shown to undergo more extensive oxygenation at its secondary carbon atoms than it did in the autoxidation and the Fe (acac)_3/ROOH systems. Thus, it was concluded that the reaction in the Fe (ClO_4)_3/H_2O_2/CH_3CN system involves both radical and non-radical processes.
- 社団法人日本薬学会の論文
- 1983-04-25
著者
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林 透
Faculty Of Pharmaceutical Sciences Hokkaido University
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三浦 敏明
Faculty Of Pharmaceutical Sciences Hokkaido University
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武藤 俊樹
Faculty of Pharmaceutical Sciences, Hokkaido University
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木村 道也
Faculty of Pharmaceutical Sciences, Hokkaido University
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浦野 千津子
Faculty of Pharmaceutical Sciences, Hokkaido University
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武藤 俊樹
Faculty Of Pharmaceutical Sciences Hokkaido University
-
木村 道也
Faculty Of Pharmaceutical Sciences Hokkaido University
-
浦野 千津子
Faculty Of Pharmaceutical Sciences Hokkaido University
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