AN UNUSUAL FLUORIDE-MEDIATED OXIDATION OF GITOXIN

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概要

• 論文の詳細を見る

• An unusual oxidative transformation of α, β-unsaturated γ-lactone of the cardenolide gitoxin (1a) by tetra-n-butylammonium fluoride (TBAF) is reported. The structure of the product (2a) was finally confirmed by an X-ray crystal structure analysis of its genin (2b). The oxidation proceeded also in the presence of CsF, and KF + 18-crown-6.

• 公益社団法人日本薬学会の論文
• 1996-01-15

著者

• 中村 康彦

  Department Of Formulation Research Dainippon Pharmaceutical Co. Ltd.

• 橋本 忠

  北陸大・薬

• 橋本 忠

  北陸大学薬学部

• HASHIMOTO Toshihiro

  Faculty of Pharmaceutical Sciences, Tokushima Bunri University

• ASAKAWA Yoshinori

  Faculty of Pharmaceutical Sciences, Tokushima Bunri University

• Asakawa Y

  Fac. Of Pharmaceutical Sciences Tokushima Bunri Univ.

• Nagatsu Akito

  Faculty Of Pharmaceutical Sciences Nagoya City University

• Ueda T

  Faculty Of Agriculture Saga University

• HATANO Keiichiro

  Faculty of Pharmaceutical Sciences, Nagoya City University

• Nagai S

  Hokuriku Univ. Kanazawa Jpn

• Nagai Shin-ichi

  Faculty Of Pharmaceutical Sciences Nagoya City University

• SAKAKIBARA Jinsaku

  Faculty of Pharmacy, Meijo University

• Nakamura Yoshihide

  Technical Department Fuji Chemical Industries Co. Ltd.

• UEDA Taisei

  Faculty of Pharmaceutical Sciences, Nagoya City University

• NAKAMURA Yukitaka

  Faculty of Pharmaceutical Sciences, Nagoya City University

• TAKEMOTO Kouya

  Faculty of Pharmaceutical Sciences, Nagoya City University

• Takemoto K

  Faculty Of Pharmaceutical Sciences Nagoya City University

• HATANO Keiichiro

  Graduate School of Pharmaceutical Sciences, Nagoya City University

• Hashimoto T

  Hokuriku Univ. Kanazawa Jpn

• Hatano K

  Graduate School Of Pharmaceutical Sciences Nagoya City University

• Hatano Keiichiro

  Faculty Of Pharmaceutical Sciences Nagoya City University

• Asakawa Y

  Tokushima Bunri Univ. Tokushima Jpn

• Asakawa Yoshinori

  Faculty Of Pharmaceutical Sciences Tokushima Bunri University

• Hashimoto Toshihiro

  Faculty Of Pharmaceutical Sciences Tokushima Bunri University

• Hashimoto Toshihiro

  Fac. Of Pharmaceutical Sciences Tokushima Bunri Univ.

• Nakamura Y

  Department Of Pharmacognosy Tohoku Pharmaceutical University

• Sakakibara J

  Faculty Of Pharmaceutical Sciences Nagoya City University

• Sakakibara Jinsaku

  Faculty Of Pharmaceutical Sciences Nagoya City University

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