A New Lignan, (-)-Berchemol, from Berchemia racemosa
スポンサーリンク
概要
- 論文の詳細を見る
A new tetrahydrofuranoid lignan, named (-)-berchemol (1), mp 188-189 ℃, [α] D -7.9°, C_<20>H_<24>O_7,was isolated together with a known lignan, (-)-secoisolariciresinol, from the stems of Berchemia racemosa SIEB. et ZUCC. (Rhamnaceae). The relative stereostructure of 1 was elucidated on the basis of chemical evidence, and spectroscopic and X-ray analysis. The absolute configuration of 1 was determined by comparison of its circular dichroism spectrum with that of (-)-olivil. (-)-Berchemol was determined to be (2R, 3S, 4S)-2,4-bis(4-hydroxy-3-methoxyphenyl)-3-hydroxy-3-hydroxymethyltetrahydrofuran.
- 社団法人日本薬学会の論文
- 1989-12-25
著者
-
河合 賢一
星薬大
-
桜井 信子
東北大学薬学部
-
河合 賢一
Faculty of Pharmaceutical Sciences, University of Tokyo
-
井上 隆夫
星薬科大学
-
河合 賢一
星薬科大学
-
河合 賢一
Faculty Of Pharmaceutical Sciences Hoshi University
-
桜井 信子
星薬科大学生薬学教室
-
井上 隆夫
Faculty of Pharmaceutical Sciences Hoshi University
-
桜井 信子
Faculty of Pharmaceutical Sciences, Hoshi University
-
長嶋 新一
Faculty of Pharmaceutical Sciences, Hoshi University
-
長嶋 新一
Faculty Of Pharmaceutical Sciences Hoshi University
-
Sakurai N
Faculty Of Pharmaceutical Sciences Hoshi University
-
Inoue Takao
Hoshi College of Pharmacy
-
井上 隆夫
星薬科大学薬学部
関連論文
- 35 Emericella heterothallicaの産生する新規エピポリチオジオキソピペラジン誘導体およびその関連化合物(口頭発表の部)
- Cimicifuga属植物の成分研究(第12報)Acerinolの構造改訂と関連化合物の構造
- Cimicifuga属植物の成分研究(第11報)Dahurinol, Dehydroxyahurinol, Isodahurinol, 25-O-Methylisodahurinolの単離と立体構造
- Chemical Studies on the Oriental Plant Drugs. XXVII. The Acid Catalyzed Reactions and the Absolute Configuration at C_ of Dammarane Type Triterpenes
- Isolation and Structures of Antibacterial Binaphtho-α-pyrones, Talaroderxines A and B, from Talaromyces derxii
- STRUCTURE REVISION OF MYCOTOXIN, VIRIDITOXIN, AND ITS DERIVATIVES
- 78(P-73) 細胞内情報伝達系に作用する南米産薬用植物の成分研究(ポスター発表の部)
- Structures of a New Dihydroxanthone Derivative, Nidulalin A, and a New Benzophenone Derivative, Nidulalin B, from Emericella nidulans
- ABSOLUTE STRUCTURE OF (+)-13β-HYDROXYMAMANITE, A POSSIBLE METABOLINE OF (-)-BAPTIFOLINE
- 1,3-Dipolar Cycloaddition Reactions of Thiazolo[5,4-d]pyrimidine 1-0xides with Acetylenic Esters Involving New Ring Transformations of the Thiazole Nucleus(Organic,Chemical)
- Michael Reactions of 4-Acylmethylene-1,3 (2H, 4H)-isoquinolinediones with Malononitrile
- Michael Reactions of 3-Acylmethyleneoxindoles with Active Methylene Compounds
- Synthetic Study of the Ginseng Sapogenins : Preparation of Dammarenediol-II and Remote Oxidation of Dammaranediols with Photoexcited Nitrobenzene Derivatives
- Isolation and Structures of Two New Indoloditerpenes Related to Aflavinine from a Microsclerotium-Producing Strain of Aspergillus flavus
- Aspergillus novofumigatus から分離されたジヒドロテレインおよびテレインの血小板凝集作用に関する検討
- マルブランキア・フィラメントサから得られる2種の新規フラノン誘導体
- 好乾性真菌Aspergillus restrictus A17株のアレルゲン活性
- ブラジル土壌より分離されたアスペルジルス・フミガツスIFM 54246株から得られた抗真菌活性物質
- ネオサルトリア・フィッシェリからのイソテレインの単離
- 研究課題'04-23 真菌からの生理活性物質の探索(平成16年度 共同利用研究報告)
- 120(P-74) 未同定真菌IFM52672からの抗真菌物質の分離と構造決定(ポスター発表の部)
- 468 気管支喘息患者における好乾菌Asperugillus restrictus RAST 陽性率の検討
- 467 好乾菌Aspergillus restrictusの産生するアレルゲン活性検討
- A New Azaphilone, Falconensin H, from Emericella falconensis
- Falconensins A, B, C, and D, New Compounds Related to Azaphilone, from Emericella falconensis
- Structures of New Indoloditerpenes, Possible Biosynthetic Precursors of the Tremorgenic Mycotoxins, Penitrems, from Penicillium crustosum
- Sterochemistry of an 18,22-Cyclosterol, Mer-NF8054X, from Emericella heterothallica and Aspergillus ustus
- Structures of Novel Epipolythiodioxopiperazines, Emethallicins B, C, and D, Potent Inhibitors of Histamine Release, from Emericella heterothallica
- Structure of a Novel Epidithiodioxopiperazine, Emethallicin A, a Potent Inhibitor of Histamine Release, from Emericella heterothallica
- Studies on Fungal Products. XVIII. : Isolation and Structures of a New Fungal Depsidone Related to Nidulin and a New Phthalide from Emericella unguis
- Studies on Fungal Products. XVI. : New Metabolites Related to 3-Methylorsellinate from Aspergillus silvaticus
- Studies on the Constituents of Aceraceae Plants. V. Two Diarylheptanoid Glycosides and an Arylbutanol Apiosylglucoside from Acer nikoense
- Studies on the Constituents of Aceraceae Plants. IV. Carbon-13 Nuclear Magnetic Resonance Spectra of Acerogenin A, Rhododendrol and Related Compounds, and Structure of Aceroside IV from Acer nikoense
- Studies on the Constituents of Aceraceae Plants. III. Strucure of Acerogenin B from Acer nikoense MAXIM.
- 38 メグスリノキより得られる2つの新しいヘテロサイド : diarylheptanolとarylbutanolのapiosylglucosides
- Studies on the Constituents of Aceraceae Plants. II. Structure of Aceroside I, a Glucoside of a Novel Cyclic Diarylheptanoid from Acer nikoense MAXIM.
- カエデ科植物の成分研究(第1報)メグスリノキの葉および樹皮の成分
- ヤチヤナギからの新規トリテルペノイドMyricalactone及び数種のトリテルペノイド
- THREE NOVEL CYCLOLANOSTANOL XYLOSIDES FROM CIMICIFUGA RHIZOME
- Electrochemical Methoxylation of Arylacetates
- A New Lignan, (-)-Berchemol, from Berchemia racemosa
- A Novel Electrochemical Synthesis of Ureides from Esters
- Isolation of a New Tremorgenic Indologiterpene, 1'-O-Acetylpaxilline, from Emericella striata and Distribution of Paxilline in Emericella spp.
- 84(PA3-4) Emericella属菌類の生産する新規インドロジテルペン誘導体Emindole類およびその関連化合物(ポスター発表の部)
- A Novel Electrochemical Method of Acetylation of Alcohols by Methyl Acetate(Organic,Chemical)
- Studies on Fungal Products. XI. Isolation and Structures of Novel Cyclic Pentapeptides from Aspergillus sp. NE-45(Organic,Chemical)
- キクニガナ及びスギナより得られたカフェー酸エステルの血管平滑筋弛緩作用
- 生薬升麻の基源であるサラシナショウマ属及び近縁植物の成分
- Diarylheptanoids from Myrica gale var. tomentosa and Revised Structure of Porson
- Studies on the Chinese Crude Drug "Shoma." X. Three New Trinor-9,19-cyclolanostanol Xylosides, Cimicifugosides H-3,H-4 and H-6,from Cimicifuga Rhizome and Transformation of Cimicifugoside H-1 into Cimicifugosides H-2,H-3 and H-4
- Studies on the Chinese Crude Drug "Shoma". IX. Three Novel Cyclolanostanol Xylosides, Cimicifugosides H-1,H-2 and H-5,from Cimicifuga Rhizome
- 実験的肝障害に対するクマヤナギの防護効果
- Studies on the Chinese Crude Drug "Shoma." VIII. Two New Triterpenol Bisdesmosides, 3-Arabinosyl-24-O-acetylhydroshengmanol 15-Glucoside and 3-Xylosyl-24-O-acetylhydroshengmanol 15-Glucoside, from Cimicifuga dahurica
- Studies on the Constituents of Beesia calthaefolia and Souliea vaginata. IV. Beesioside I, a Cyclolanostanol Xyloside from the Rhizomes of Beesia calthaefolia
- 実験的肝障害に対する楊梅皮の防護効果(生薬学)
- Berchemolide, a Novel Dimeric Vanillic Acid Glucoside from Berchemia racemosa
- 各種生薬メタノールエキスのラット四塩化炭素肝障害防護効力
- 放射線障害防護薬剤に関する研究(第30報)川〓中の放射線障害防護物質
- 放射線障害防護薬剤に関する研究(第26報)放射線皮膚障害に対する各種生薬の防護効果
- Constituents of Myrica rubra. III. : Structures of Two Glycosides of Myricanol
- 放射線障害防護薬剤に関する研究(第25報)生薬類の放射線障害防護効力
- Studies on the Constituents of Beesia calthaefolia and Souliea vaginata. II. : Beesioside II, a Cyclolanostanol Xyloside from Rhizomes of Beesia calthaefolia
- 放射線障害防護薬剤に関する研究(第24報)四物湯の放射線障害防護効力
- Microbial Reduction of 2-Phenylpropionic Acid, 2-Benzyloxypropionic Acid and 2-(2-Furfuryl) propionic Acid
- Microbial Reduction and Resolution of Herbicidal 2-Alkyl-2-aryloxyacetic Acids by Gloeosporium olivarum
- Studies on the Constituents of Aceraceae Plants. VII. : Diarylheptanoids from Acer griseum and Acer triflorum
- Studies on the Constituents of Aceraceae Plants. VI. : Revised Stereochemistry of (-)-Centrolobol, and New Glycosides from Acer nikoense
- ^C-核磁気共鳴スペクトルにおけるオルト置換フェノールのO-メチル化効果(第2報)
- O-Methylation Effect on the Carbon-13 Nuclear Magnetic Resonance Signals of ortho-Disubstituted Phenols and Its Application to Structure Determination of New Phthalides from Aspergillus silvaticus
- Carbon-13 Nuclear Magnetic Resonance Spectral Study. Effect of O-Methylation of ortho-Substituted Phenols on the Aryl Carbon Shielding and Its Application to Interpretation of the Spectra of Some Flavonoids
- ニオイイリスの成分研究(第1報)地下部に含まれるC-Glucosylxanthoneの単離およびそれらの生合成
- センブリに含まれるフラボン-C-配糖体の生合成
- Protosappanin A, a Novel Biphenyl Compound from Sappan Lignum
- 6 Emericella属菌類の生産する抗真菌性エピジチオジオキソピペラジン誘導体Emestrinおよびその関連化合物
- Studies on the Constituents of Aceraceae Plants. XII. Two New Diarylheptanoid Glycosides from Acer triflorum
- 生薬「升麻」に関する研究(第7報)北升麻および同属近縁植物からの真正配糖体Acetyl Shengmanol Xyloside, 24-O-Acetylhydroshengmanol XylosideおよびShengmanol Xylosideの単離と定量
- 生薬「升麻」に関する研究(第6報)サラシナショウマ属トリテルペン配糖体の新しい真正配糖体Shengmanol Xyloside
- Studies on the Chinese Crude Drug "Shoma."V. Structures of 24-O-Acetylhydroshengmanol Xyloside and 22-Hydroxycimigenol Xyloside
- タラロマイセス・フラブスIFM52668株から得られる新フニコン誘導体
- ナガバノコウヤボウキから得られるセスキテルペノイドと青葉アルコール配糖体及びコウヤボウキのセスキテルペン配糖体
- アスペルジルス属菌IFM51759株から得られたフラノン及びピラノン誘導体のアスペルジルス・フミガツスに対する抗真菌活性
- Studies on the Constituents of Aceraceae Plants. XI. Two Types of Cyclic Diarylheptanoid from Acer nikoense
- 知母のサポニン成分について
- New Glucosides of a 4-Hydroxy-5-methylcoumarin and a Dihydro-α-pyrone from Gerbera jamesonii hybrida
- Cyanogenic Glycosides and 4-Hydroxycoumarin Glycosides from Gerbera jamesonii hybrida
- Studies on Fungal Products. IX. : Dethiosecoemestrin, a New Metabolite Related to Emestrin, from Emericella striata
- 14 EBELIN LACTONE形成サポニンの真正サポゲニンについて
- 楊梅皮のDiarylheptanoid
- Bitter Principles of Pertya glabrescens : Two Sesquiterpene Glucosides
- New Sesquiterpene Dilactone from Pertya glabrescens
- Two Glycosides of a Novel Dammarane Alcohol from Gynostemma pentaphyllum
- Syntheses of Two Microbial Metabolites, 5-Chloro-3,4-dihydro-8-hydroxy-6-methoxy-3-methylisocoumarin and 8-Hydroxy-6-methoxy-3-methylisocoumarin
- 過ヨード酸およびシクロヘキシルアミンによる配糖体の加水分解法およびその糖部-非糖部結合決定の可能性
- メグスリノキ及びヤマモモの成分.Diarylheptanoidを中心として
- Sambucus属植物の成分研究(第2報)エゾニワトコ葉の成分
- Studies on the Chinese Crude Drug "Shoma." IV. Structure of Acetyl Shengmanol Xyloside, a Probable Precursor of some Known Cimicifuga Glycosides
- 生薬「升麻」に関する研究(第3報)イヌショウマのトリテルペン配糖体および25-Anhydrocimigenol Arabinosideの構造
- イチジク葉の血圧下降成分
- 生薬「升麻」に関する研究(第1報) : 北升麻および和升麻(黒升麻)よりフェノールカルボン酸の分離
- センボンヤリの4-ヒドロキシクマリン配糖体