Studies on the Constituents of Aceraceae Plants. II. Structure of Aceroside I, a Glucoside of a Novel Cyclic Diarylheptanoid from Acer nikoense MAXIM.
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概要
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The structure of aceroside I, C_<25>H_<32>O_8,mp 170-171°(acetone), [α]^<20>_D-7.7°, which was isolated from the stem bark of Acer nikoense MAXIM. (Aceraceae), was established to be acerogenin A β-D-glucopyranoside represented by formula 1. Acerogenin A, C_<19>H_<22>O_3,mp 151-152°, [α]^<20>_D+57.3°, was concluded to be a m-, p'-bridged diphenyl ether type diarylheptanoid (2) on the basis of chemical and spectroscopic (especially NMR) evidences. The stereostructure of 2 was determined by derivation of acerogenin A (2) into (S)-1-(p-hydroxyphenyl)-7-(p-methoxyphenyl)-heptan-3-ol. Acerogenin A (2) is the first example of a novel type of diarylheptanoid-20-oxa-[7,1]-metapara-cyclophane.
- 社団法人日本薬学会の論文
- 1978-09-25
著者
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永井 正博
星薬科大学
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久保 正良
Faculty Of Pharmaceutical Sciences Hoshi University:(present Address)tsumura Laboratory
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井上 隆夫
星薬科大学
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井上 隆夫
Hoshi College of Pharmacy
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永井 正博
星薬大
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松尾 光芳
Tokyo Metropolitan Institute of Gerontology
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藤田 正雄
Faculty Of Pharmaceutical Sciences:hoshi University
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藤田 正雄
星薬科大学薬学部:(現)株式会社ウチダ和漢薬研究開発室
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