Isomerization of Linoleic Acid Hydroperoxides under Argon and under Degassed Conditions
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概要
- 論文の詳細を見る
The rearrangement of linoleic acid hydroperoxides, (9Z, 11E)-13-hydroperoxy-9,11-and (9E, 11E)-13-hydroperoxy-9,11-octadecadienoic acids (13-Z, E-LOOH and 13-E, E-LOOH, respectively), occurred under argon and under degassed conditions, as well as under aerobic conditions. In argon-saturated benzene, 13-Z, E-LOOH isomerized to 9-E, E-and 13-E, E-LOOHs, and 13-E, E-LOOH to 9-E, E-LOOH ; the E, E-isomers hardly isomerized to E, Z-isomers. The hydroperoxides isomerized rapidly in benzene and chloroform, but slowly in n-propyl ether and methanol. However, they decomposed extensively in chloroform, and moderately in benzene and methanol. Decomposition was very slight in n-propyl ether. The isomerization rate of the 9Z, 11E-isomer was much higher than that of the 9E, 11E-isomer. Since the rate was found to be slow under degassed conditions, traces of dissolved molecular oxygen may be responsible for the isomerization.
- 公益社団法人日本薬学会の論文
- 1984-01-25
著者
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金子 孝夫
東京都老人研
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松尾 光芳
Tokyo Metropolitan Institute of Gerontology
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松尾 光芳
甲南大・理
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金子 孝夫
Tokyo Metropolitan Institute of Gerontology
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