Rearrangement in Halogenation of 2-Phenylethanol
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概要
- 論文の詳細を見る
The halogenation of 2-phenylethanol-1-^<14>C and -1-^<13>C was carried out with halogenphosphorus or phosphorus trihalide under various conditions. The resulting 2-phenylethyl halides showed isotopic scrambling of the ^<14>C and ^<13>C label from C-1 to C-2. The degree of rearrangement increased with the rise of reaction temperature. In a given temperature, the rearrangement in iodination was more than that found in bromination or chlorination.
- 公益社団法人日本薬学会の論文
- 1977-05-25
著者
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金子 孝夫
東京都老人研
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松尾 光芳
Tokyo Metropolitan Institute of Gerontology
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松尾 光芳
甲南大・理
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金子 孝夫
Tokyo Metropolitan Institute of Gerontology
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