A Facile Synthetic Approach for Alkyl α-Glycosides of Reducing Disaccharides
スポンサーリンク
概要
- 論文の詳細を見る
Methanolysis and benzyl alcoholysis of β-cellobiosyl, or β-lactosyl, or β-maltosyl N, N-dimethyldithiocarbamate in the presence of mercuric chloride and cadmium carbonate were investigated. Methyl and benzyl glycosides formation proceeded in good yield under mild conditions, in which formation of α-anomer was always predominant over that of β-anomer : in methanolysis, the ratios of α-and β-anomers were about 4 : 1 and in benzyl alcoholysis, 2 : 1,respectively. Using this method methyl α-cellobioside, α-lactoside, and α-maltoside were synthesized. The procedure is a facile synthetic method for appropriate alkyl α-glycosides of reducing disaccharides.
- 社団法人日本薬学会の論文
- 1978-05-25
著者
-
石原 英子
名古屋市立大学
-
手島 節三
名古屋市立大学薬学部
-
石原 英子
Faculty of Pharmaceutical Sciences, Nagoya City University
-
手島 節三
Faculty of Pharmaceutical Sciences, Nagoya City University
-
鄭 大基
Faculty of Pharmaceutical Sciences, Nagoya City University
-
手島 節三
Faculty Of Pharmaceutical Sciences Nagoya City University
-
鄭 大基
Faculty Of Pharmaceutical Sciences Nagoya City University
関連論文
- サンドイッチ酸素抗体法による食品中のカラギーナンの測定
- サンドイッチ酵素抗体法によるカラギーナンの測定について
- HPLCによる特定保健用食品等中のオリゴ糖の測定法
- 唾液中プロスタグランディンD_2とマタニティブルーズ発症予測
- 御供泰治教授の定年ご退職によせて(御供泰治教授定年ご退職記念特集)
- 植物油(リノール酸)の摂り過ぎに対する警告
- ゲル濾過を用いた食品添加物カラギーナン中の単糖, 二糖の定量
- 酵素法による食品中グルコース, フルクトース, ショ糖の同時定量
- アスパラギン結合型糖蛋白質糖鎖の部分合成 (糖質--その反応,合成,機能および利用特集号)
- Synthesis of 2-Acetamido-4-O-(2-acetamido-2-deoxy-β-D-glucopyranosyl)-2-deoxy-3-O-(α-L-fucopyranosyl)-D-glucopyranose (3-O-α-L-Fucopyranosyl-di-N-acetylchitobiose)
- Chemical Modification of Lactose. XIII. Synthesis of Lacto-N-tetraose
- A Preparation of the Branched Trisaccharide 2-Acetamido-2-deoxy-4-O-(β-D-galactopyranosyl)-3-O-(β-D-xylopyranosyl)-D-glucopyranose (3-O-β-D-Xylopyranosyl-N-acetyllactosamine)
- Chemical Modification of Lactose. XII. Preparation of O-(2-Acetamido-2-deoxy-β-D-glucopyranosyl)-(1→6)-O-β-D-galactopyranosyl-(1→4)-D-glucopyranose (6´-N-Acetylglucosaminyllactose)
- 女子薬学生に期待する
- Synthesis of Methyl O-β-D-Galactopyranosyl-(1→6)-O-α-D-galactopyranosyl-(1→6)-O-α-D-galactopyranosyl-(1→6)-O-β-D-glucopyranoside
- Chemical Modification of Lactose. IX. Synthesis of O-β-D-Galactopyranosyl-(1→6)-O-β-D-galactopyranosyl-(1→4)-D-glucopyranose (6'-Galactosyllactose)
- A Facile Synthetic Approach for Alkyl α-Glycosides of Reducing Disaccharides
- 膵リパーゼ活性におよぼす胆汁酸塩の影響
- The Lipase-Catalyzed Reaction of n-Alkyl n-Butyrates with Methanol
- Analytical Studies on Esterases using Gas-Liquid Chromatography. II. On the Alcoholytic and Hydrolytic Activities of Esterases from Swine Liver and Mucor javanicus
- Simultaneous Determination of Ethanol and Carbon Dioxide by Two-Order Microdiffusion Analysis and Its Application to Analysis of Alcoholic Fermentation
- オリゴ糖添加食品中の機能性オリゴ糖類の含有量
- 蓮糸の主成分について
- コウリャン色素溶液の生理的水素イオン濃度における変化
- ベニバナ黄色素溶液の生理的水素イオン濃度における変化
- シソ色素溶液の生理的水素イオン濃度における変化
- Chemical Modification of Lactose. XIII. Synthesis of Lacto-N-tetraose
- マルチトールのイソプロピリデン化反応とα-グリコシド結合を持つ二糖類の新合成経路
- New Syntheses of 6-Deoxy-L-gulose and 6-Deoxy-L-talose
- Chemical Modification of Maltose. VII. Synthesis of 4-O-(2-Acetamido-2-deoxy-α-D-glucopyranosyl)-D-glucopyranose (GlcNAcα1→4Glc)
- Chemical Modification of Maltose. VI. Selective p-Toluenesulfonylation of 1,6-Anhydro-4', 6'-O-benzylidene-β-maltose using Phase Transfer Catalysis
- Chemical Modification of Maltose. V. A New Synthesis of 2-Acetamido-2-deoxy-4-O-α-D-glucopyranosyl-α-D-glucopyranose (N-Acetylmaltosamine)
- Chemical Modification of Maltose. IV. Synthesis of 4-O-α-D-Altropyranosyl-D-glucopyranose
- Chemical Modification of Maltose. III. Selective p-Toluenesulfonylation of 1,6-Anhydro-4', 6'-O-benzylidene-β-maltose
- Studies on Catalytic Hydrogenation of the Exocyclic Double Bond in Reducing Disaccharides
- Selective Benzoylation of 1,6-Anhydro-4', 6'-O-benzylidene-β-maltose
- Syntheses of 4-O-α-D-Galactopyranosyl-D-glucopyranose and 4-O-(6-Deoxy-α-D-galactopyranosyl)-D-glucopyranose by Chemical Modifications of Maltose
- Thiosugars. XVII. Syntheses of Maltose Derivatives having Sulfur Atom in the Reducing Moiety
- 糖の科学に魅せられて
- Thiosugars. XVIII. : Synthesis of 2-Acylamino-1,6-anhydro-2,6-dideoxy-6-thio-β-D-glucopyranose
- Thiosugars. XV. Further Contribution on Anomalous High Reactivity of Secondary Methanesulfonic Esters in Thiosugars
- Thiosugars. VI. Reaction Products of Potassium Alkyl- and Benzylxanthates with Acetylated Glucosyl Halides.
- A Novel Synthesis of Trehalose-Type Thiodisaccharides. An Anomalous Reaction of Potassium Methyl-and Benzyl-xanthates with Halogeno-O-acetyl Sugars in Acetone
- Synthesis of 2-Acetamido-4-O-(2-acetamido-2-deoxy-β-D-glucopyranosyl)-2-deoxy-6-O-(α-L-fucopyranosyl)-D-glucopyranose (6-O-α-L-Fucopyranosyl-di-N-acetylchitobiose)
- A New Synthesis of 2-Acetamido-4-O-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranosyl)-1,3,6-tri-O-acetyl-2-deoxy-α-D-glucopyranose (Chitobiose Octaacetate)
- Syntheses of O-α-and O-β-D-Galactopyranosyl-(1→6)-O-[α-D-glucopyranosyl-(1→4)]-D-glucopyranoses
- Synthesis of O-α-and O-β-D-Galactopyranosyl-(1→6)-O-α-D-glucopyranosyl-(1→4)-D-glucopyranoses
- Chemical Modification of Lactose. V. Synthesis of 6'-Acetamido-6'-deoxy-α-lactose
- Chemical Modification of Lactose. IV. Syntheses of Disaccharide Derivatives Predominantly Modified at the C-6 Position in Lactose
- Chemical Modification of Lactose. III. Syntheses of 4'-Acetamido-4'-deoxy-α-lactose and 6'-Acetamido-6'-deoxy-α-cellobiose
- Thiosugars. XVI. Synthesis of Cellobiose Derivatives having Sulfur Atom in the Reducing Moiety
- In Vivo and in Vitro Antitumor Activity of Sugars containing Sulfur
- Studies on the Fischer's Glucal-hydrobromid-diacetat and Glucal-hydrobromid-triacetat
- Thiosugars. XIV. Studies on the Syntheses of 1,2-Dideoxy-1,2-dithioimidocarbonyl-β-D-mannopyranose and 1,2-Dideoxy-1,2-trithiocarbonyl-β-D-mannopyranose
- Thiosugars. XIII. An Attempt at Thiosugar Synthesis having a Vicinal cis-Dimercapto Group in the Pyranose Ring
- Thiosugars. XII. Studies on Unsaturated Sugars derived from Glucosyl N, N-Dimethyldithiocarbamate.
- Thiosugars. XI. Further Studies on Thiolevoglycosans.
- Studies on the Fischer's Glucal-hydrobromid-diacetat and Glucal-hydrobromid-triacetat
- オリゴ糖の1,6-アンヒドロ誘導体の^C Nuclear Magnetic Resonanceスペクトル
- ラクト-N-テトラオース誘導体の^C-Nuclear Magnetic Resonanceスペクトル
- Syntheses of Acetylated Trisaccharides, Manα1→3Manβ1→4GlcNAc and Manα1→2Manβ1→4GlcNAc, relating to Mannosidosis
- 含硫糖類の抗腫瘍性
- On the Relative Rates of Displacement Reaction of Primary p-Tosyloxy Groups of Hexapyranose Derivatives with Sodium Iodide in Acetone Solution.
- Biochemical Studies on Thiosugars. IV. Synthesis of 1,6-Anhydro-1,6-sulfide-β-D-glucopyranose (Thiolevoglucosan) and 6-Deoxy-6-mercapto-1-thio-D-glucose.
- Synthesis of Anomers of 6-O-Tosyl-1,3,4-tri-O-acetyl-N-acetyl-D-glucosamine and 1,6-Anhydro-N-acetyl-β-D-glucosamine.
- A New Synthesis of 1,6-Anhydro-β-D-glucopyranose (Levoglucosan).
- Biochemical Studies on Thiosugars. III. Synthesis of 6-Deoxy-6-mercapto-D-glucose.
- Reaction Products of Glucuronic Acid with Phenylhydrazine.
- Biochemical Studies on Thiosugars. II. Synthesis of N-Acetyl-1-thio-D-glucosamine and its Derivatives.
- Biochemical Studies on Thiosugars. I. Synthesis of 1-Thio-D-glucuronic Acid.
- オクテット
- Syntheses of Acetylated Tetrasaccharides, Manα1→2Manα1→3Manβ1→4GlcNAc and Manα1→3Manα1→6Manβ1→4GlcNAc
- 乳糖の反応および人乳オリゴ糖と類似体合成の試み
- Syntheses of 2-Acetamido-2-deoxy-4-O-β-D-galactopyranosyl-D-glucopyranose (N-Acetyllactosamine) Derivatives
- Chemical Modification of Lactose. XVII. Syntheses of O-α- and O-β-L-Fucopyranosyl-(1→4)- or -(1→6)-O-β-D-galactopyranosyl-(1→4)-D-glucopyranoses (4'- or 6'-O-α- and -O-β-L-Fucopyranosyllactoses)
- Synthesis of 2-Acetamido-1,6-anhydro-3-O-benzyl-2-deoxy-β-D-glucopyranose, a Useful Glycosyl Acceptor for 1,4-Linked, N-Acetylglucosaminecontaining Oligosaccharides Synthesis
- オリゴ糖-L-アスパラギン化合物の合成 (糖質の化学)
- 糖タンパク質の糖鎖部の有機合成
- Chemical Modification of Lactose. XVI. : Synthesis of Lacto-N-neohexaose
- Chemical Modification of Lactose. XV. Syntheses of O-α- and O-β-L-Fucopyranosyl-(1→3)-O-β-D-galactopyranosyl-(1→4)-D-glucopyranoses (3'-O-α- and 3'-O-β-L-Fucopyranosyllactoses)
- Chemical Modification of Lactose. XIV. Synthesis of O-2-Acetamido-2-deoxy-β-D-glucopyranosyl-(1→3)-O-[2-acetamido-2-deoxy-β-D-glucopyranosyl-(1→6)]-O-β-D-galactopyranosyl-(1→4)-β-D-glucopyranose (3', 6'-Di-β-N-acetylglucosaminyl-β-lactose)
- Chemical Modification of Lactose. XVI. Synthesis of Lacto-N-neohexaose
- Chemical Modification of Lactose. XI. A New Synthesis of 2-Acetamido-2-deoxy-4-O-β-D-galactopyranosyl-α-D-glucopyranose (N-Acetyllactosamine)
- Chemical Modification of Lactose. VIII. Studies on the Reactivities of the Secondary Hydroxyl Groups in 1,6-Anhydro-4', 6'-O-benzylidene-β-lactose by Selective p-Toluenesulfonylation
- 食品添加物と消化酵素作用(第4報) : 着色料とトリプシンその3
- 食品添加物と消化酵素作用(第3報) : 着色料とトリプシンその2
- Thiosugars. V. Synthesis of 1-Thio-β-D-ribopyranose and 1-Thio-β-D-mannopyranose Derivatives
- Thiosugars. VII. Synthesis of 1-Thio-2-deoxy-β-D-glucose Derivatives
- A New Synthesis of α-L-Fucose
- Chemical Modification of Lactose. X. Syntheses of 4-O-(3-O-Methyl-β-D-idopyranosyl)-D-glucopyranose and 4-O-(3-Deoxy-β-D-lyxo-hexopyranosyl)-D-glucopyranose
- Chemical Modification of Lactose. VII. Synthesis of 4-O-β-D-Idopyranosyl-D-glucopyranose
- Chemical Modification of Lactose. VII. Synthesis of 4-0-β-D-Idopyranosyl-D-glucopyranose
- 衛生対策研究(III) : 大気汚染除去に関する基礎資料(2) : 海水電解液による空気中の二酸化イオウの中和処理および水蒸気による空気中の二酸化イオウの吸収
- 食物繊維定量法の検討 : Neutral Detergent法と酵素-重量法について
- アスパラギン結合型糖蛋白質糖鎖の部分合成
- Chlorella vulgaris成分の利用研究(第5報) : 藻体外に分泌されたCarbohydraseについてその2
- Multi-Order Microdiffusion Analysis
- 拡散分析の衛生化学的応用研究(IV) : 食品中の亜硫酸塩類の定量
- 教養部とじゅうぶん話合いたい(薬学生の一般教育をより意義あるものにするためには)
- 糖の化学をめぐる30年