Thiosugars. VI. Reaction Products of Potassium Alkyl- and Benzylxanthates with Acetylated Glucosyl Halides.

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概要

• 論文の詳細を見る

• When potassium alkyl- or benzylxanthate was reacted on acetylated D-glucopyranosyl halides in ethanol or in acetone, acetylated D-glucopyranosyl xanthates, acetylated di-D-glucopyranosyl sulfides, and acetylated β-D-thioglucosides formed. The yield of each condensation products was affected by choice of solvent, the reaction temperature, the potassium xanthate, and starting halide used. A simple method for the preparation of bis (2,2', 3,3', 4,4', 6,6'-octa-O-acetyl-β, β'-D-glucopyranosyl) sulfide (octa-O-acetyl-isothiotrehalose) was confirmed by the reaction of potassium methyl- or benzylxanthate upon 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide. Two other isomers of octa-O-acetyl-isothiotrehalose were synthesized as crystalline forms.

• 社団法人日本薬学会の論文
• 1964-06-25

著者

• 阪田 正勝

  東日本学園大学薬学部

• 阪田 正勝

  Faculty Of Pharmaceutical Sciences Hokkaido University

• 赤木 満洲雄

  Faculty of Pharmaceutical Sciences, School of Medicine, Hokkaido University

• 手島 節三

  Faculty of Pharmaceutical Sciences, Nagoya City University

• 羽賀 正信

  東日本学園大学薬学部

• 羽賀 正信

  Faculty of Pharmaceutical Sciences, School of Medicine, Hokkaido University, Nishi-5-chome, Kita-12-

• 手島 節三

  Faculty Of Pharmaceutical Sciences Nagoya City University

• 羽賀 正信

  公立昭和病院

• Haga M

  Faculty Of Pharmaceutical Sciences Health Sciences University Of Hokkaido

• Haga Masanobu

  Faculty Of Pharmaceutical Sciences Hokkaido University

• 羽賀 正信

  Faculty Of Pharmaceutical Sciences Health Sciences University Of Hokkaido

• 赤木 満洲雄

  Faculty Of Pharmaceutical Sciences Hokkaido University

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