New Syntheses of 6-Deoxy-L-gulose and 6-Deoxy-L-talose

スポンサーリンク

概要

• 論文の詳細を見る

• Treatment of methyl 2,3,4,-tri-O-benzoyl-6-deoxy-6-iodo-α-D-mannopyranoside (1) or methyl 4-O-acetyl-2,3-di-O-benzoyl-6-deoxy-6-iodo-α-D-allopyranoside (11) with silver fiuoride in pyridine gave the corresponding D-lyxo- (2) or D-ribo-hex-5-enoside (12), respectively. Catalytic hydrogenation of these 5-enosides yielded preferentially the 6-deoxy-L-gulo derivative (4) from the D-lyxo-5-enoside (2) and the 6-deoxy-L-talo derivative (14) from the D-ribo-5-enoside (12). Zemplen deacylation followed by acid hydrolysis of the acylated glycosides afforded 6-deoxy-L-gulose and 6-deoxy-L-talose. The product ratios upon hydrogenation of the 5-enoside derivatives with several kinds of catalysts were measured by high-performance liquid chromatography and results are summarized in Tables I and II. The proton and carbon-13 nuclear magnetic resonance spectral data of the products are also discussed.

• 社団法人日本薬学会の論文
• 1986-10-25

著者

• 森 雅美

  金城学院大学薬学部

• 森 雅美

  名古屋市立大学看護学部(生化学)

• 森 雅美

  愛知きわみ看護短期大学

• 手島 節三

  名古屋市立大学薬学部

• 手島 節三

  Faculty of Pharmaceutical Sciences, Nagoya City University

• 手島 節三

  Faculty Of Pharmaceutical Sciences Nagoya City University

• 丹羽 利充

  Department Of Internal Medicine Nagoya University Branch Hospital

• 森 雅美

  Faculty of Pharmaceutical Sciences, Nagoya City University

関連論文

• サンドイッチ酸素抗体法による食品中のカラギーナンの測定
• サンドイッチ酵素抗体法によるカラギーナンの測定について
• 医療現場の医療裁判事例に基づく再現劇画を用いた倫理教育の教材開発
• [専門領域別応募課題研究発表]医療における倫理教育の実態とあり方 : 医療訴訟事例に基づく医療現場を再現した医療倫理教育の教材化
• 01P3-065 安全な医療提供と院内薬品の適正管理4 : 院内での消毒および消毒薬管理の実態と薬剤師の役割(薬品管理、使用状況調査,医療薬学の扉は開かれた)
• 安全な医療提供と院内薬品の適正管理 : 5. 消毒および消毒薬に対する看護職者の意識と問題
• 医療における倫理教育の実態とあり方 : 資格試験からみた医療職種間の医療倫理教育
• 看護教育における「消毒」の扱いへの提言--看護学生の消毒・消毒薬に対する意識調査から
• 舌ブラッシングによる高齢者の味覚感受性変化
• 米国における医師の専門職倫理教育--現状と課題
• ゲル濾過を用いた食品添加物カラギーナン中の単糖, 二糖の定量
• 酵素法による食品中グルコース, フルクトース, ショ糖の同時定量
• アスパラギン結合型糖蛋白質糖鎖の部分合成 (糖質--その反応,合成,機能および利用特集号)
• Synthesis of 2-Acetamido-4-O-(2-acetamido-2-deoxy-β-D-glucopyranosyl)-2-deoxy-3-O-(α-L-fucopyranosyl)-D-glucopyranose (3-O-α-L-Fucopyranosyl-di-N-acetylchitobiose)
• Chemical Modification of Lactose. XIII. Synthesis of Lacto-N-tetraose
• A Preparation of the Branched Trisaccharide 2-Acetamido-2-deoxy-4-O-(β-D-galactopyranosyl)-3-O-(β-D-xylopyranosyl)-D-glucopyranose (3-O-β-D-Xylopyranosyl-N-acetyllactosamine)
• Chemical Modification of Lactose. XII. Preparation of O-(2-Acetamido-2-deoxy-β-D-glucopyranosyl)-(1→6)-O-β-D-galactopyranosyl-(1→4)-D-glucopyranose (6´-N-Acetylglucosaminyllactose)
• Synthesis of Methyl O-β-D-Galactopyranosyl-(1→6)-O-α-D-galactopyranosyl-(1→6)-O-α-D-galactopyranosyl-(1→6)-O-β-D-glucopyranoside
• Chemical Modification of Lactose. IX. Synthesis of O-β-D-Galactopyranosyl-(1→6)-O-β-D-galactopyranosyl-(1→4)-D-glucopyranose (6'-Galactosyllactose)
• A Facile Synthetic Approach for Alkyl α-Glycosides of Reducing Disaccharides
• The Lipase-Catalyzed Reaction of n-Alkyl n-Butyrates with Methanol
• Analytical Studies on Esterases using Gas-Liquid Chromatography. II. On the Alcoholytic and Hydrolytic Activities of Esterases from Swine Liver and Mucor javanicus
• 薬剤師の薬学的介入がリチウム中毒の進行を防いだ症例
• 医療現場の医療裁判事例に基づく再現劇画を用いた倫理教育の教材開発
• Chemical Modification of Lactose. XIII. Synthesis of Lacto-N-tetraose
• シドニー大学看護学部での本学学生の研修 : 平成14年度研修に対する参加学生の評価について
• シドニー大学看護学部での本学学生の研修 : 平成14年度研修の事前準備と実態
• P-380 医薬品の適正使用と薬剤師の役割 3 医療用漢方製剤の適正使用に対する病院薬剤師の認識
• マルチトールのイソプロピリデン化反応とα-グリコシド結合を持つ二糖類の新合成経路
• New Syntheses of 6-Deoxy-L-gulose and 6-Deoxy-L-talose
• Chemical Modification of Maltose. VII. Synthesis of 4-O-(2-Acetamido-2-deoxy-α-D-glucopyranosyl)-D-glucopyranose (GlcNAcα1→4Glc)
• Chemical Modification of Maltose. VI. Selective p-Toluenesulfonylation of 1,6-Anhydro-4', 6'-O-benzylidene-β-maltose using Phase Transfer Catalysis
• Chemical Modification of Maltose. V. A New Synthesis of 2-Acetamido-2-deoxy-4-O-α-D-glucopyranosyl-α-D-glucopyranose (N-Acetylmaltosamine)
• Chemical Modification of Maltose. IV. Synthesis of 4-O-α-D-Altropyranosyl-D-glucopyranose
• Chemical Modification of Maltose. III. Selective p-Toluenesulfonylation of 1,6-Anhydro-4', 6'-O-benzylidene-β-maltose
• Studies on Catalytic Hydrogenation of the Exocyclic Double Bond in Reducing Disaccharides
• Selective Benzoylation of 1,6-Anhydro-4', 6'-O-benzylidene-β-maltose
• Syntheses of 4-O-α-D-Galactopyranosyl-D-glucopyranose and 4-O-(6-Deoxy-α-D-galactopyranosyl)-D-glucopyranose by Chemical Modifications of Maltose
• Thiosugars. XVII. Syntheses of Maltose Derivatives having Sulfur Atom in the Reducing Moiety
• ピラツォロン誘導体の合成研究(第18報) : 1,2,4,5,6,7-Hexahydro-3H-pyrazolo[4,3-c]pyridine類の合成
• 糖の科学に魅せられて
• Thiosugars. XVIII. : Synthesis of 2-Acylamino-1,6-anhydro-2,6-dideoxy-6-thio-β-D-glucopyranose
• Thiosugars. XV. Further Contribution on Anomalous High Reactivity of Secondary Methanesulfonic Esters in Thiosugars
• Thiosugars. VI. Reaction Products of Potassium Alkyl- and Benzylxanthates with Acetylated Glucosyl Halides.
• A Novel Synthesis of Trehalose-Type Thiodisaccharides. An Anomalous Reaction of Potassium Methyl-and Benzyl-xanthates with Halogeno-O-acetyl Sugars in Acetone
• Synthesis of 2-Acetamido-4-O-(2-acetamido-2-deoxy-β-D-glucopyranosyl)-2-deoxy-6-O-(α-L-fucopyranosyl)-D-glucopyranose (6-O-α-L-Fucopyranosyl-di-N-acetylchitobiose)
• A New Synthesis of 2-Acetamido-4-O-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranosyl)-1,3,6-tri-O-acetyl-2-deoxy-α-D-glucopyranose (Chitobiose Octaacetate)
• Syntheses of O-α-and O-β-D-Galactopyranosyl-(1→6)-O-[α-D-glucopyranosyl-(1→4)]-D-glucopyranoses
• Synthesis of O-α-and O-β-D-Galactopyranosyl-(1→6)-O-α-D-glucopyranosyl-(1→4)-D-glucopyranoses
• Chemical Modification of Lactose. V. Synthesis of 6'-Acetamido-6'-deoxy-α-lactose
• Chemical Modification of Lactose. IV. Syntheses of Disaccharide Derivatives Predominantly Modified at the C-6 Position in Lactose
• Chemical Modification of Lactose. III. Syntheses of 4'-Acetamido-4'-deoxy-α-lactose and 6'-Acetamido-6'-deoxy-α-cellobiose
• Thiosugars. XVI. Synthesis of Cellobiose Derivatives having Sulfur Atom in the Reducing Moiety
• In Vivo and in Vitro Antitumor Activity of Sugars containing Sulfur
• Studies on the Fischer's Glucal-hydrobromid-diacetat and Glucal-hydrobromid-triacetat
• Thiosugars. XIV. Studies on the Syntheses of 1,2-Dideoxy-1,2-dithioimidocarbonyl-β-D-mannopyranose and 1,2-Dideoxy-1,2-trithiocarbonyl-β-D-mannopyranose
• Thiosugars. XIII. An Attempt at Thiosugar Synthesis having a Vicinal cis-Dimercapto Group in the Pyranose Ring
• Thiosugars. XII. Studies on Unsaturated Sugars derived from Glucosyl N, N-Dimethyldithiocarbamate.
• Thiosugars. XI. Further Studies on Thiolevoglycosans.
• Studies on the Fischer's Glucal-hydrobromid-diacetat and Glucal-hydrobromid-triacetat
• オリゴ糖の1,6-アンヒドロ誘導体の^C Nuclear Magnetic Resonanceスペクトル
• ラクト-N-テトラオース誘導体の^C-Nuclear Magnetic Resonanceスペクトル
• 回復者主導型の薬物依存症回復施設(DARC)を巡る研究の動向
• 回復者主導型の薬物依存症回復施設に向けた新しい回復支援策の立案に関する研究 : ある施設の日常活動調査と顕在化した課題
• わが国における女性アルコール依存症を巡る諸問題
• 平成15年度シドニー大学看護学部学生研修に関する報告
• 名古屋市立大学看護学部とシドニー大学との学術交流 : はじまりとその具体化作業
• 学部実習生・研修生の積極的な受け入れこそ効果的な研修 (MH forum懸賞論文 薬剤師の資質向上のための生涯研修の進め方) -- (入選論文)
• Syntheses of Acetylated Trisaccharides, Manα1→3Manβ1→4GlcNAc and Manα1→2Manβ1→4GlcNAc, relating to Mannosidosis
• 含硫糖類の抗腫瘍性
• On the Relative Rates of Displacement Reaction of Primary p-Tosyloxy Groups of Hexapyranose Derivatives with Sodium Iodide in Acetone Solution.
• Biochemical Studies on Thiosugars. IV. Synthesis of 1,6-Anhydro-1,6-sulfide-β-D-glucopyranose (Thiolevoglucosan) and 6-Deoxy-6-mercapto-1-thio-D-glucose.
• Synthesis of Anomers of 6-O-Tosyl-1,3,4-tri-O-acetyl-N-acetyl-D-glucosamine and 1,6-Anhydro-N-acetyl-β-D-glucosamine.
• A New Synthesis of 1,6-Anhydro-β-D-glucopyranose (Levoglucosan).
• Biochemical Studies on Thiosugars. III. Synthesis of 6-Deoxy-6-mercapto-D-glucose.
• オクテット
• Syntheses of Acetylated Tetrasaccharides, Manα1→2Manα1→3Manβ1→4GlcNAc and Manα1→3Manα1→6Manβ1→4GlcNAc
• 乳糖の反応および人乳オリゴ糖と類似体合成の試み
• Syntheses of 2-Acetamido-2-deoxy-4-O-β-D-galactopyranosyl-D-glucopyranose (N-Acetyllactosamine) Derivatives
• Chemical Modification of Lactose. XVII. Syntheses of O-α- and O-β-L-Fucopyranosyl-(1→4)- or -(1→6)-O-β-D-galactopyranosyl-(1→4)-D-glucopyranoses (4'- or 6'-O-α- and -O-β-L-Fucopyranosyllactoses)
• Synthesis of 2-Acetamido-1,6-anhydro-3-O-benzyl-2-deoxy-β-D-glucopyranose, a Useful Glycosyl Acceptor for 1,4-Linked, N-Acetylglucosaminecontaining Oligosaccharides Synthesis
• オリゴ糖-L-アスパラギン化合物の合成 (糖質の化学)
• 糖タンパク質の糖鎖部の有機合成
• Chemical Modification of Lactose. XVI. : Synthesis of Lacto-N-neohexaose
• Chemical Modification of Lactose. XV. Syntheses of O-α- and O-β-L-Fucopyranosyl-(1→3)-O-β-D-galactopyranosyl-(1→4)-D-glucopyranoses (3'-O-α- and 3'-O-β-L-Fucopyranosyllactoses)
• Chemical Modification of Lactose. XIV. Synthesis of O-2-Acetamido-2-deoxy-β-D-glucopyranosyl-(1→3)-O-[2-acetamido-2-deoxy-β-D-glucopyranosyl-(1→6)]-O-β-D-galactopyranosyl-(1→4)-β-D-glucopyranose (3', 6'-Di-β-N-acetylglucosaminyl-β-lactose)
• Chemical Modification of Lactose. XVI. Synthesis of Lacto-N-neohexaose
• Chemical Modification of Lactose. XI. A New Synthesis of 2-Acetamido-2-deoxy-4-O-β-D-galactopyranosyl-α-D-glucopyranose (N-Acetyllactosamine)
• Chemical Modification of Lactose. VIII. Studies on the Reactivities of the Secondary Hydroxyl Groups in 1,6-Anhydro-4', 6'-O-benzylidene-β-lactose by Selective p-Toluenesulfonylation
• 食品添加物と消化酵素作用(第4報) : 着色料とトリプシンその3
• 食品添加物と消化酵素作用(第3報) : 着色料とトリプシンその2
• A New Synthesis of α-L-Fucose
• Chemical Modification of Lactose. X. Syntheses of 4-O-(3-O-Methyl-β-D-idopyranosyl)-D-glucopyranose and 4-O-(3-Deoxy-β-D-lyxo-hexopyranosyl)-D-glucopyranose
• Chemical Modification of Lactose. VII. Synthesis of 4-O-β-D-Idopyranosyl-D-glucopyranose
• Chemical Modification of Lactose. VII. Synthesis of 4-0-β-D-Idopyranosyl-D-glucopyranose
• 食物繊維定量法の検討 : Neutral Detergent法と酵素-重量法について
• アスパラギン結合型糖蛋白質糖鎖の部分合成
• 教養部とじゅうぶん話合いたい(薬学生の一般教育をより意義あるものにするためには)
• 糖の化学をめぐる30年
• 急性期病院における病棟看護師の退院支援に関する自己評価

もっと見る 閉じる

スポンサーリンク