Biochemical Studies on Thiosugars. I. Synthesis of 1-Thio-D-glucuronic Acid.

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概要

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• 1-Thio-β-D-glucopyranurono-6,1-thiolactone was prepared by hydrolysis of methyl 2,3,4-tri-O-acetyl-1-thio-β-D-glucopyranuronate 1-ethylthionocarbonate which was prepared from methyl 2,3,4-tri-O-acetyl-1-bromo-1-deoxy-α-D-glucopyranuronate and potassium ethylxanthate. Methylation of this compound with diazomethane and subsequent acetylation afforded methyl (methyl 2,3,4-tri-O-acetyl-1-thio-β-D-glucopyranosid) uronate.

• 公益社団法人日本薬学会の論文
• 1960-12-25

著者

• 赤木 満洲雄

  Faculty of Pharmaceutical Sciences, School of Medicine, Hokkaido University

• 手島 節三

  Faculty of Pharmaceutical Sciences, Nagoya City University

• 羽賀 正信

  Faculty of Pharmaceutical Sciences, School of Medicine, Hokkaido University, Nishi-5-chome, Kita-12-

• 手島 節三

  Faculty Of Pharmaceutical Sciences Nagoya City University

• 羽賀 正信

  Faculty Of Pharmaceutical Sciences Nagoya City University

• 羽賀 正信

  Faculty Of Pharmaceutical Sciences Health Sciences University Of Hokkaido

• 赤木 満洲雄

  Faculty Of Pharmaceutical Sciences Hokkaido University

関連論文

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• Studies on Metabolism of 2-Methyl-3-o-tolyl-4 (3H)-quinazolinone. I. The Estimation of 2-Methyl-3-o-tolyl-4 (3H)-quinazolinone in Biological Materials.
• Synthesis of 2-Acetamido-4-O-(2-acetamido-2-deoxy-β-D-glucopyranosyl)-2-deoxy-3-O-(α-L-fucopyranosyl)-D-glucopyranose (3-O-α-L-Fucopyranosyl-di-N-acetylchitobiose)
• Chemical Modification of Lactose. XIII. Synthesis of Lacto-N-tetraose
• A Preparation of the Branched Trisaccharide 2-Acetamido-2-deoxy-4-O-(β-D-galactopyranosyl)-3-O-(β-D-xylopyranosyl)-D-glucopyranose (3-O-β-D-Xylopyranosyl-N-acetyllactosamine)
• Chemical Modification of Lactose. XII. Preparation of O-(2-Acetamido-2-deoxy-β-D-glucopyranosyl)-(1→6)-O-β-D-galactopyranosyl-(1→4)-D-glucopyranose (6´-N-Acetylglucosaminyllactose)
• Synthesis of Methyl O-β-D-Galactopyranosyl-(1→6)-O-α-D-galactopyranosyl-(1→6)-O-α-D-galactopyranosyl-(1→6)-O-β-D-glucopyranoside
• Chemical Modification of Lactose. IX. Synthesis of O-β-D-Galactopyranosyl-(1→6)-O-β-D-galactopyranosyl-(1→4)-D-glucopyranose (6'-Galactosyllactose)
• A Facile Synthetic Approach for Alkyl α-Glycosides of Reducing Disaccharides
• The Lipase-Catalyzed Reaction of n-Alkyl n-Butyrates with Methanol
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• Structure of p-Ethoxyphenylurea-N-glucuronide
• Chemical Modification of Lactose. XIII. Synthesis of Lacto-N-tetraose
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• Chemical Modification of Maltose. III. Selective p-Toluenesulfonylation of 1,6-Anhydro-4', 6'-O-benzylidene-β-maltose
• Studies on Catalytic Hydrogenation of the Exocyclic Double Bond in Reducing Disaccharides
• Selective Benzoylation of 1,6-Anhydro-4', 6'-O-benzylidene-β-maltose
• Syntheses of 4-O-α-D-Galactopyranosyl-D-glucopyranose and 4-O-(6-Deoxy-α-D-galactopyranosyl)-D-glucopyranose by Chemical Modifications of Maltose
• Thiosugars. XVII. Syntheses of Maltose Derivatives having Sulfur Atom in the Reducing Moiety
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• Thiosugars. XVIII. : Synthesis of 2-Acylamino-1,6-anhydro-2,6-dideoxy-6-thio-β-D-glucopyranose
• ISOLATION OF LIMONIN AND OBACUNONE FROM PHELLODENDRI CORTEX SHORTEN THE SLEEPING TIME INDUCED IN MICE BY α-CHLORALOSE-URETHANE
• Studies on the Constitution of Edible and Medicinal Plants. I. : Isolation and Identification of 4-O-Methylpyridoxine, Toxic Principle from the Seed of Ginkgo biloba L.
• AN ANTIVITAMIN B_6,4'-METHOXYPYRIDOXINE, FROM THE SEED OF GINKGO BILOBA L.
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• Biochemical Studies on Thiosugars. I. Synthesis of 1-Thio-D-glucuronic Acid.
• Syntheses of Acetylated Tetrasaccharides, Manα1→2Manα1→3Manβ1→4GlcNAc and Manα1→3Manα1→6Manβ1→4GlcNAc
• Syntheses of 2-Acetamido-2-deoxy-4-O-β-D-galactopyranosyl-D-glucopyranose (N-Acetyllactosamine) Derivatives
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