Thiosugars. V. Synthesis of 1-Thio-β-D-ribopyranose and 1-Thio-β-D-mannopyranose Derivatives

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概要

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• Crystalline product obtained by the reaction of potassium ethylxanthate upon an anomeric mixture of 2,3,4-tri-O-acetyl-D-ribopyranosyl bromides or that of 2,3,4,6-tetra-O-acetyl-D-mannopyranosyl bromides in anhydrous acetone was confirmed to be one anomer of 2,3,4-tri-O-acetyl-D-ribopyranosyl ethylxanthates or that of 2,3,4,6-tetra-O-acetyl-D-mannopyranosyl ethylxanthates, respectively. Their anomeric configurations at carbon 1 were assumed to be β. Three derivatives of 1-thio-β-D-ribopyranose and four derivatives of 1-thio-β-D-mannopyranose were synthesized in crystalline forms from acetylated glycosyl ethylxanthates mentioned above.

• 公益社団法人日本薬学会の論文
• 1964-05-25

著者

• 赤木 満洲雄

  Faculty of Pharmaceutical Sciences, School of Medicine, Hokkaido University

• 手島 節三

  Faculty of Pharmaceutical Sciences, Nagoya City University

• 手島 節三

  Faculty Of Pharmaceutical Sciences Nagoya City University

• 槇 孝雄

  Faculty of Pharmaceutical Sciences, Hokkaido University

• 赤木 満洲雄

  Faculty Of Pharmaceutical Sciences Hokkaido University

関連論文

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• Synthesis of Methyl O-β-D-Galactopyranosyl-(1→6)-O-α-D-galactopyranosyl-(1→6)-O-α-D-galactopyranosyl-(1→6)-O-β-D-glucopyranoside
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