8,13a-Propanoberbines. III. Reaction of Acetoneberberine Type Enamine with Alkyl Halide
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概要
- 論文の詳細を見る
The reaction of acetoneberberine (I) with methyl iodide was found to give 8,13a-(2'-oxopropano)-13,13-dimethylberbine derivative (IV) and 8,13a-(2'-oxopropano)-13-methylberbine derivative (V) as side products together with the expected 13-methyl-berberinium (II) and berberinium iodide (III). Analogous reaction of I with allyl bromide gave rise to 8,13a-(2'-oxopropano)-13,13-diallylberbine derivative (XI). The structures of products were deduced from chemical and spectral data.
- 社団法人日本薬学会の論文
- 1975-06-25
著者
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金子 秀彦
Research Laboratories Dainippon Pharmaceutical Co. Ltd.
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西村 温樹
Research Laboratories:dainippon Pharmaceutical Co. Ltd.
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西村 温樹
Research Laboratories Dainippon Pharmaceutical Co. Ltd.
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成戸 俊介
Research Laboratories Dainippon Pharmaceutical Co. Ltd
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成戸 俊介
Exploratory Research Laboratories Dainippon Pharmaceutical Co. Ltd.
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