Metal Complexes of Isonicotinoylhydrazine and Related Compounds. I. Consecutive Formation Constants of Isonicotinoylhydrazine-Cd (II) Complexes Determined from Polarographic Data.
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概要
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Consecutive formation constants of Cd (II) complexes of isonicotinoylhydrazine (INH) were determined by the polarographic method. A series of solutions containing 0.001M Cd^<2+>, 1.0M NaNO_3 and INH in concentration varying from 0.05 to 1.0M were used for the measurement of i_d and E_<1/2>. The method of De Ford and Hume was modified for calculation of concentration equilidrium constants K_j'. The results were [numerical formula] These results, especially K'_3,however, did not agree with the constants obtained by pH titration method which will be shown in the later report.
- 公益社団法人日本薬学会の論文
- 1963-06-25
著者
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長野 晃三
Faculty of Pharmaceutical Sciences, University of Tokyo
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田村 善蔵
Faculty Of Pharmaceutical Sciences University Of Tokyo
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長野 晃三
Faculty Of Pharmaceutical Sciences University Of Tokyo
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