Metal Complexes of Isonicotinoyltydrazine and Related Compounds. IV. Composition Formulae and Infrared Absorption Spectra of Metal Complex Crystals of Isonicotinoylhydrazine and Related Compounds
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概要
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The following complexes were isolated by mixing metal chloride and ligand in water or ethanol. Their composition formulae were determined from the data of elemental analyses and their complex types are shown in parentheses. INH-Cu(MZ) ; INH-Cd(M(HZ)_2) ; NH-Cu(MZ) ; PH-Cu(MHZ and MZ) ; BH-Cu(MHZ) ; BH-Cd(MHZ); PNBH-Cu(MZ) ; INA-Cu(M(HZ)_2) ; N-Me-INH-Cu(MHZ) ; NA-Cu(M(HZ)_2) ; PA-Cu(MHZ). The infrared spectra of these complexes were investigated by comparing with those of ligands themselves and those of N-deuterated metal complexes. The behavior of the main hands (the bands of amide I, II, and III, NH_2 deformation and pyridine ring vibrations) were discussed in relation to the structure of the complexes and their constitutional formulae were postulated.
- 公益社団法人日本薬学会の論文
- 1964-10-25
著者
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平川 暁子
Faculty Of Pharmaceutical Sciences University Of Tokyo
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長野 晃三
Faculty of Pharmaceutical Sciences, University of Tokyo
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木下 恒
Faculty of Pharmaceutical Sciences, University of Tokyo
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木下 恒
Faculty Of Pharmaceutical Sciences University Of Tokyo
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長野 晃三
Faculty Of Pharmaceutical Sciences University Of Tokyo
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