Reflectivity and Electronic Structures of Layered Ionic Crystals,(C_nH_<2n+1>NH_3)_2CdCl_4 : n=1,2,3
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概要
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The reflection spectra of (C.H....NH.).CdCl. were measured in the photonenergy region of 0.5-25 eV at room temperature (RT) and liquid nitrogen tempera-ture (LNT) by means of synchrotron radiation. It was found that absorption spectraof the present crystals resem ble that of CdCl. crystals except for an additional peak at5.10 eV (RT). The energy of the additional peak shifts with temperature by as muchas 0.38 eV from 5.10 eV (RT) to 5.48 eV (LNT). This absorption peak has doubletstructure and the splitting energy is 0.1 eV, which is the same magnitude as the spinorbit splitting of a chlorine atom. The band is assigned to be an electronic transitionfrom the chlorine 3p valence band to a new-type conduction band which is composedof alkylammonium bases and is below the ordinary Cd 5.s conduction band in energy.[optical reflection spectra, layered ionic crystal, two-dimensional crystal, alkylam- ll monium cadmium chloride, optical constant, synchrotron radiationl
- 社団法人日本物理学会の論文
- 1989-07-15
著者
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Nanba T
Graduate School Of Science And Technology Kobe University
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NANBA Takao
Department of Physics and Graduate School of Science and Technology, Kobe University
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Aoyagi Kiyoshi
Department of Public health, Graduate School of Biomedical Sciences, Nagasaki University
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YOSHINARI Takehisa
Department of Physics, Faculty of Science, Yamagata University
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Aoyagi Kiyoshi
Department Of Physics Faculty Of Science Yamagata University
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SHIMANUKI Shigetaka
Osaka Women's University
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MATSUYAMA Tomochika
Research Reactor Institute,Kyoto University
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Fujisawa Masami
Radiation Laboratory,Institute for Solid State Physics,The University of Tokyo
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Ikezawa Mikihiko
Research Institute for Scientific Measurements,Tokyo University
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Ikezawa M
Tohoku Univ. Sendai
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Ikezawa Mikihiko
Research Institute For Scientific Measurements Tokyo University
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Nanba Takao
Faculty Of Science Kobe University
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Yoshinari Takehisa
Department Of Physics Faculty Of Science Yamagata University
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Yoshinari Takehisa
Department Of Physics Faculty Of Science Tohoku University
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Fujisawa Masami
Institute For Solid State Physics University Of Tokyo
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Fujisawa Masami
Synchrotron Radiation Laboratory The Institute For Solid State Physics University Of Tokyo
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Fujisawa Masami
The Institute For Solid State Physics The University Of Tokyo
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Fujisawa Masami
The Synchrotron Radiation Laboratory The Institute For Solid State Physics The University Of Tokyo
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Matsuyama Tomochika
Research Reactor Institute Kyoto University
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Aoyagi Kiyoshi
Department Of Orthopaedic Surgery Mitsugi Public General Hospital
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Aoyagi K
Department Of Physics Faculty Of Science Yamagata University
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Shimanuki S
Department Of Environmental Sciences Faculty Of Science Osaka Women's University
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Ikezawa Mikihiko
Research Institute For Scientific Measurements Tohoku University
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Yoshinari T
Department Of Physics Faculty Of Science Yamagata University
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