Optical Excitation of the Rotational Transition of Methane in Condensed Rare Gas Matrices
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概要
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The far-infrared optical absorption spectra of CFI. and CD. molecules dilutedin condensed Xe, Kr and Ar have been obtained at 6 K. The isotope shifts of ther>eak enern>' showed that observed absorption bands are due to rotational transi-tions and vibrational ones of the substituted molecules. In the Xe matrix thevibrational absorption band has not been found. The observed peak positions ofthe rotational transitions are compared with a theoretical calculation byNishiyama and Yamamoto. The agreement between the experiment and thetheory is good in the case of the Xe matrix but poor in the Kr and Ar xmatrices.The discrepancy is discussed in relatiout to the intensity of the vibrational band.
- 社団法人日本物理学会の論文
- 1980-01-15
著者
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NANBA Takao
Department of Physics and Graduate School of Science and Technology, Kobe University
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Nanba Takao
Department Of Physics Faculty Of Science Tohoku University
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Ikezawa Mikihiko
Department Of Physics The Faculty Of Science Tohoku University
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Ikezawa Mikihiko
Department Of Physics Faculty Of Science Tohoku University
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Ikezawa Mikihiko
Department Of Physics Faculity Of Science Tohoku University
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SAGARA Minoru
Department of Physics,Faculty of Science,Tohoku University
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Sagara Minoru
Department Of Physics Faculty Of Science Tohoku University
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Ikezawa Mikihiko
Department of Physics,Faculty of Science,Tohoku University
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