Pressure-Temperature Phase Diagram of Triammonium Hydrogen Disulfate (NH_4)_3H (SO_4)_2
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The pressure-temperature phase diagram of (NO.).FI(SO.). was studied by meansof dielectric and differential thermal analysis measurements in a range of p $8.5 kbar, lOO'C $7'$150'C.TheI-Iltransitionpoint(140'Cat 1 aim) linearly decreases withincreasing hydrostatic pressure with a slope of -5.76 deg kbar '. The pressuredependence of the II-III transition point is expressed by a quadratic equatuonT.=T':-F-Kp-I-'7p' with parameters of 7':= -8.J'C, K= -3.7deg kbar ', and7= -0.13 deg kbar '. Two pressure-induced ferroelectric phases (Phases Vl, Vll) arefound above about 5kbar. The II-III-Vl triple point is found at 7v=7.Okbar,T= -4O.5'C
- 社団法人日本物理学会の論文
- 1977-08-15
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