Reinvestigation of Pressure-Induced II-III Transitions in Ferroelectric Ca_2r (C_2H_5COO)_6 and Ca_2Pb (C_2H_5COO)_6
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The pressure induced ferroelectric II to ferroelectric III phase transitions inCazSr(C.lI5C00). (DSP) and Ca.Pb(C.H.C00). (DIP) crystals were reinves-tigated by polarizing microscope observation and dielectric constant measure-ments. The phase transitions were observed without passing through the firstorder phase boundaries to avoid possible effects of strains. At room temperaturetransitions- from optically uniaxial to biaxial states were found at 0.68.1-0.10GPa in DSP and 0.60.J.0.]O GPa in DLP. Dielectric constant measurementsindicated that the transition in DLP corresponds to the II-III transition while thatin DSP to a new pressure induced phase of IV. The results indicate that phase IIIin DLP is not isostructural with phase II in contrast to early expectation.
- 社団法人日本物理学会の論文
- 1984-05-15
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